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Chemistry (CHEM)

83 courses in the 1988–89 Undergraduate Calendar, read from the scanned original. The text comes from OCR, so check the scanned page before relying on a detail.

CHEM 001 Pre-University Chemistry

The course covers the material considered essential preparation for first year chemistry courses. Included are formulae, nomenclature, stoichiometry, an introduction to thermochemistry, solution chemistry, chemical equilibria, acids, bases, oxidation-reduction reactions, kinetics and bonding.

Successful completion of this course fulfills the University Admission requirements where high school chemistry is necessary. No University credit. Offered by correspondence only.

CHEM 10 W 1C 0

General Chemistry Seminar

Required for all Chemistry students beyond Year One, this seminar brings together students from all years to receive information concerning the activities of the Chemistry Department and The Chemical Institute of Canada, and to hear invited speakers.

YEAR 1 CHEMISTRY COURSES

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CHEM 123 Chemical Reactions, Equilibria and KineticsF 3C,1T 0.5

The stoichiometry of compounds and chemical reactions; principles of equilibria, solubility and acid-base equilibria; electrochemistry; chemical kinetics.

Prereq: Grade 13 Chemistry, Mathematics (Calculus)

Coreq: (for Science students) CHEM 123L

Antireq: CHEM 125

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CHEM 123L Chemical Reaction Laboratory 1F 3L 0.25

Selected experiments for students taking CHEM 123 or 125.

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CHEM 124 Organic Chemistry 1W,S 3C,1T 0.5

Bonding in carbon compounds. Structures, properties and nomenclature of several important classes of organic compounds. Interconversions of functional groups. Mechanisms of organic reactions.

Prereq: Grade 13 Chemistry, Mathematics (Calculus)

CHEM 123 strongly recommended

Coreq: (for Science students) CHEM 124L

Antireq: CHEM 126, 26

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CHEM 124L Chemical Reaction Laboratory 2W,S 3L 0.25

Selected experiments for students taking CHEM 124 or 126.

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CHEM 125 Chemical Reactions, Equilibria andF 3C,1T 0.5

Kinetics . An enriched version of CHEM 123 for all students in, or planning to enter, Chemistry or Biochemistry programs. Prereq: Same as for CHEM 123 Coreq: Same as for CHEM 123 Antireq: CHEM 123

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CHEM 126 Organic Chemistry 1W,S 3C,1T 0.5

An enriched version of CHEM 124 for all students in, or planning to enter, Chemistry or Biochemistry programs. Prereq: Same as for CHEM 124 Coreq: Same as for CHEM 124 Antireq: CHEM 124, 26

UPPER YEAR CHEMISTRY COURSES

CHEM 26 F,W 3C,3L 0.5 Organic Chemistry 1 Basic chemistry of aliphatic compounds; shapes of molecules. A laboratory course on preparative organic chemistry accompanies the lectures.

Prereq: Grade 13 Chemistry’

Antireq: CHEM 124, 124L, 126

For students in Year Two Engineering

CHEM 36 F,S 3C 0.5 Organic Chemistry 2 Survey of aliphatic and aromatic chem-

, istry with examples from industrial

processes; carbohydrates and other natural products.

Prereq: CHEM 26

Antireq: CHEM 264, 266, 267

For students in Year Two Engineering

Course Descriptions 16:23 Chemistry

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CHEM 212 Structure and BondingF,W 3C 0.5

Classical and wave theories of the electronic structure of atoms. The periodic table. Formation and characteristics of ionic and covalent bonds. Molecular orbital and valence bond theories. Bonding in molecular, ionic, and metallic solids. Structure and stereochemistry of simple inorganic compounds.

Prereq: Grade 13 Chemistry, Physics, completion of Year One in good standing or permission of instructor

Antireq: CHEM 218

For Honours students only

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CHEM 218 Development of Chemical Bonding and StructureF 2C,1T 0.5

Current models of bonding in Inorganic Chemistry. Prediction of stereochemistry and electronic structure. Inorganic nomenclature.

Prereq: Grade 13 Chemistry, Physics, completion of Year One in good standing or permission of instructor

Antireq: CHEM 212

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CHEM 219 Chemistry of Non-Transition ElementsW 2C,1T 0.5

Group trends in main group chemistry. Emphasis will be placed on correlation of structure with physical properties in various groups of compounds.

Prereq: CHEM 212 or 218

Antireq: CHEM 313

By correspondence only

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CHEM 220 Introductory Analytical ChemistryF,W 2C,1T 0.5

The principles underlying quantitative measurements.

Prereq: CHEM 123 or 125, 123L

Coreq: (for Science students) CHEM 220L

Antireq: CHEM 228

For Honours students only

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CHEM 220L Analytical Chemistry Laboratory 1F,W 3L 0.25

Selected experiments for students taking CHEM 220.

For Honours students only

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CHEM 221 Multi-component AnalysisF,W,S 2C 0.5

Electrochemical, spectroscopic and separation methods for the quantitative description of multi-component systems.

Prereq: CHEM 220

Coreq: (for Science students) CHEM 221L

Antireq: CHEM 228

For Honours students only

16:24 Course Descriptions Chemistry

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CHEM 221L Analytical Chemistry Laboratory 2F,W,S 6L 0.5

Selected experiments for students taking CHEM 221.

For Honours students only

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CHEM 228 Analytical Chemistry for Life SciencesW 2C,3L 0.5

Selected topics of importance to Biology students, with related experiments. - Prereq: CHEM 123 or 125, 124 or 126 Antireq: CHEM 220, 221 For students in Honours Biology only

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CHEM 237 Introductory BiochemistryF,W,S 3C 0.5

An introduction to the chemistry of amino acids, carbohydrates, lipids and nucleic acids. Structure and properties of proteins and enzymes.

Prereq: CHEM 264 or 266

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CHEM 237L Introductory Biochemistry LaboratoryF,W,S 3L 0.25

Selected experiments for students taking CHEM 237.

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CHEM 254 Physical Chemistry 1F,W 2C,1T 0.5

This course emphasizes the macroscopic approach. Areas to be studied include properties of gases; the first, second and third laws of thermodynamics applied to ideal systems; chemical equilibrium. Prereq: CHEM 123 or 125, MATH 113A/B or equivalent Antireq: CHEM 356 For Honours students only

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CHEM 255 Physical Chemistry 2F,W,S 2C,1T 0.5

Thermodynamic concepts are applied to a variety of systems, to mixtures of nonelectrolytes and to solutions of electrolytes. The difference between thermodynamic and dynamic equilibria is. introduced to deal with rates of chemical reactions and their relationship to experimental data.

Prereq: CHEM 254

For Honours students only

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CHEM 264 Organic Chemistry 2F,W 3C 0.5

Preparation and reactions of typical organic functional groups examined on the basis of reaction mechanisms. Stereochemistry of organic molecules. Prereq: CHEM 124 or 126 Antireq: CHEM 36, 266 For Honours students only

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CHEM 265 Organic Chemistry 3F,W,S 2C,1T 0.5

The detailed treatment of organic chemistry begun in CHEM 124 and 264 is continued, with further emphasis on stereochemistry, reaction mechanisms and aromaticity. Introduction to spectroscopy. Prereq: CHEM 264 Antireq: CHEM 267 For Honours students only

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CHEM 265L Organic Chemistry Laboratory 1F,W,S 3L 0.25

Selected experiments for students taking CHEM 265.

For Honours students only

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CHEM 266 Basic Organic Chemistry 2F,W 3C 0.5

More detailed discussions of the important classes of aliphatic and aromatic compounds. An extended look at stereochemistry and its importance in reaction mechanisms. . Prereq: CHEM 124 or 126 Antireq: CHEM 36, 264

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CHEM 266L Organic Chemistry LaboratoryF,W 3L 0.25

Selected experiments for students taking CHEM 266.

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CHEM 267 Basic Organic Chemistry 3W 2C 0.5

A continuation of the concepts of CHEM 266. Introduction to carbohydrates, proteins, and lipids. Introduction to NMR and IR spectroscopies.

Prereq: CHEM 266

Antireq: CHEM 36, 265

For students needing a full year of Organic Chemistry as a prerequisite to medicine, either the sequence 266/267 and 266L, or the sequence 264/265 and 265L should be selected.

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CHEM 311 RadiochemistryW 2C 0.5

An introduction to nuclear stability rules, radioactive decay processes and nuclear structure. Alpha, beta, gamma emission. Nuclear reactions, fission, production of heavy elements. Interaction of radiation with matter. Radioisotopes. Brief introduction to actinide chemistry.

Prereq: Grade 13 Chemistry, completion of Year 1 in good standing or permission of instructor

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CHEM 312 Transition Metal ChemistryF,S 2C,1T 0.5

The transition elements and their compounds. Stereochemistry of complex ions; ligand field and molecular orbital theories of metal-ligand bonding; electronic spectra and magneto-chemistry of

_ complexes; reaction mechanisms (if time

permits). Prereq: CHEM 212 Antireq: CHEM 316 For Honours students only

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CHEM 313 Chemistry of Main Group ElementsW 2C,1T 0.5

A systematic approach to the syntheses, properties, reactions and structures of compounds of the main group elements. Trends in chemical behaviour, bonding and stereochemistry. Electron-deficient compounds, the rare gases, chemistry of phosphorus, nitrogen and sulfur will be dealt with in detail. -

Prereq: CHEM 212

Antireq: CHEM 219

For Honours students only

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CHEM 314L Inorganic Chemistry Laboratory 1F,W,S 3L 0.25

An introduction to practical inorganic chemistry.

Coreq: CHEM 312 or 313

For Honours students only

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CHEM 315L Inorganic Chemistry Laboratory 2F,W 6L 0.5

Advanced experiments in inorganic chemistry.

Prereq: CHEM 314L

For Honours students only

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CHEM 316 Coordination ChemistryF 2C,1T 0.5

A basic coverage of first row transition elements for General and certain Honours students; preparation, nomenclature and general chemistry of transition metal complexes emphasizing structure, bonding, physical properties such as colour and magnetism, and chemical reactions.

Prereq: CHEM 218 or 212

Antireq: CHEM 312

By correspondence only °

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CHEM 320 Analytical Separations and Surface AnalysisW 2C 0.5

Basic principles, instrumentation and methods of analytical separations and surface analysis.

Prereq: CHEM 221 or permission of instructor

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CHEM 321L Advanced Analytical LaboratoryW 3L 0.25

Selected experiments for students of analytical chemistry.

Prereq: CHEM 221, 221L

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CHEM 332 Structural BiochemistryF,S 2C 0.5

Determination of concentration, structure and sequence of proteins, nucleic acids and polysaccharides. Protein synthesis. Enzyme kinetics. Coenzymes.

Prereq: CHEM 237

Coreq: CHEM 265 or 267

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CHEM 333 Metabolism 1F,W 2C 0.5

Metabolism of carbohydrates, lipids and amino acids. Prereq: CHEM 237 Coreq: CHEM 265 or 267

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CHEM 334L Advanced Biochemistry LaboratoryF,W 3L 0.25

Selected experiments for students taking CHEM 332 and CHEM 333.

Prereq: One term course in biochem istry beyond CHEM 237

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CHEM 350 Spect py and Molecular StructureW 2C 0.5

Introduction to concepts and applications of microwave, Raman, IR, electronic and resonance spectroscopy with respect to molecular parameters.

Prereq: CHEM 355

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CHEM 353 Introduction to Polymer ScienceF,S 3C 0.5

Basic definitions and polymer nomenclature, molecular weight averages and distributions, constitutional and configurational isomerism, rubber elasticity, stepgrowth and free radical chain growth polymerizations, emulsion polymerization. Prereq: CHEM 254, 264 or equivalents Antireq: CH E 542

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CHEM 355 Physical Chemistry 3F,W,S 2C,1T 0.5

Introduction to the microscopic description of physical processes, laws governing electrons and atoms and the properties of atomic and molecular states, application to electromagnetic tadiation interacting with atoms and molecules producing transitions between states.

Prereq: CHEM 255, MATH 215 or equivalent

Antireq: PHYS 354

For Honours students only

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CHEM 355L Physical Chemistry Laboratory 1F,W,S 3L 0.25

Selected experiments for students taking CHEM 355.

For Honours students only

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CHEM 356 General Physical ChemistryF,S 2C,1T 0.5

An introductory survey of the thermodynamics of ideal systems, the application of thermodynamic principles to the study of solutions, phase equilibria, chemical equilibrium and the properties of electrolytes.

Prereq: CHEM 123 or 125, MATH 113A/B or equivalent

Antireq: CHEM 254

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CHEM 356L General Physical Chemical Laboratory 1F,W 3L 0.25

Selected experiments for students who have taken CHEM 356.

Prereq: CHEM 356

A special section in Winter term will be available for Honours Biochemistry students only.

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CHEM 357 Physical Chemistry for the Life SciencesW 2C\1T 0.5

Ani introductory survey of kinetic molecular theory and transport phenomena with applications to biological systems. Chemical kinetics. Some spectroscopies important to life sciences.

Prereq: CHEM 123 or 125, MATH 113A/B or equivalent

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CHEM 357L General Physical Chemistry Laboratory 2W 3L 0.25

Selected experiments for students taking CHEM 3857.

Prereq: CHEM 356L

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CHEM 358 Physical Chemistry 4F,W 2C,1T 0.5

The statistical nature of large assemblies of atoms and molecules, kinetic theory of gases, transport processes, the collision theory and transition state theory of chemical kinetics.

Prereq: CHEM 355

For Honours students only

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CHEM 358L Physical Chemistry Laboratory 2F,W 6L 0.5

Selected experiments for students taking CHEM 358.

Prereq: CHEM 355L

For Honours students only

Course Descriptions 16:25 Chemistry

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CHEM 362 Mechanistic Organic ChemistryW (even years) 2C 0.5

Simple molecular orbital theories and their use in organic chemistry. Effects of substituents and reaction conditions on the mechanism of organic reactions.

Prereq: CHEM 265

Coreq: CHEM 368

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CHEM 363 Applied Organic ChemistryW 2C 0.5

The organic chemistry involved in

selected industrial processes will be

discussed. Petroleum chemistry.

synthesis of dyestuffs, pharmaceuticals.

pesticides, organic polymers, etc. Prereq: CHEM 265 or 267

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CHEM 366 Structural and Synthetic Organic ChemistryF 2C 0.5

Stereochemistry in organic reactions; synthesis of selected organic compounds examined, in detail with emphasis on cyclo-addition reactions and condensation reactions.

Prereq: CHEM 265 or 267

Antireq: CHEM 368

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CHEM 366L Organic Chemistry LaboratoryF 3L 0.25

Selected experiments for students taking CHEM 366.

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CHEM 368 Organic Chemistry 4F,W,S 2C 0.5

The design of organic syntheses, and especially the formation of enolate ions and their use in the formation of new carbon-carbon bonds. Acidity and basicity of organic molecules. Stereochemical concepts applied to organic molecules as well as conformational analysis.

Prereq: CHEM 265

Antireq: CHEM 366

For Honours students only

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CHEM 368L Organic Chemistry Laboratory 2F,W,S 6L 0.5

Selected experiments for students taking CHEM 368.

For Honours students only

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CHEM 380 Chemical Problem Solving by ComputerF,W 1C,3T 0.5

Analysis of chemical problems, development of mathematical and numerical models and algorithms, implementation of programs using procedure-oriented languages (BASIC, FORTRAN, PASCAL), simulations and calculations on chemical processes, data reduction and treatment. Prereq: CS 102 or equivalent, good standing in Year Two or higher of a chemistry program. Formerly CHEM 280

16:26 Course Descriptions Chemistry

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CHEM 392A Research Project 1F,W,S 9L 0.75

For students in the Honours Chemistry (Thesis Option) program.

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CHEM 392B Research Project 2F,W,S 18L 1.5

For students in the Honours Chemistry (Thesis Option) program.

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CHEM 395 History of ChemistryW (odd years only) 3C 0.5

The development of chemistry will be traced from alchemy to the 20th century. The contributions of famous scientists to the concepts and models of modern chemistry will be emphasized.

Prereq: Completion of two years of a Chemistry Honours program

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CHEM 407 Industrial ChemistryF 2C 0.5

Given entirely by invited lecturers from a broad spectrum of chemistry-related industries. The range of topics will include current industrial laboratory practice, the laboratory/plant interface, and the handling of large quantities of materials.

Strongly recommended for all chemistry majors.

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CHEM 409 Solid State ChemistryW (odd years only) 2C 0.5

Packing in solids; metals, alloys and molecular crystals; ionic and covalent solids; chemical factors affecting crystal structures; properties of metals, semiconductors and molecular crystals.

Prereq: CHEM 312 or 313

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CHEM 411 Organometallic ChemistryF 2C 0.5

The synthesis, characterization and reac-

tivity of compounds containing metal-

carbon covalent bonds. Metal carbonyls

and their derivatives. Olefin, acetylene.

pi-arene and related complexes. The

nature of the metal-carbon bond. Cata-

lysis by transition metal organometallics. Prereq: CHEM 312

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CHEM 417 Inorganic Cage CompoundsW (odd years only) 2C 0.5

The synthesis, structure and reactions of selected groups of important cage compounds such as metal clusters, metalloboranes, boranes, and carboranes will be considered. The emphasis is on current literature. The course is available on a special self-study basis or by regular lectures.

Prereq: CHEM 312 or 313

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CHEM 419 Biological Aspects of InorganicW 2C 0.5

Chemistry

Metalloproteins and other metal-

containing biological molecules in hydro-

lytic enzymes; redox reactions, nitrogen

fixation and oxygen transport; the role of

alkali and alkaline earth metal cations. Prereq: CHEM 312 or 316

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CHEM 420 Analytical ChemistryW 2C 0.5

Selected topics in modern analysis of inorganic materials such as rocks, ores, ceramics, metals and alloys; atomic flame spectroscopic methods, analytical X-ray techniques, methods for ultrapure materials, trace and micro determinations.

Prereq: CHEM 221 or permission of instructor

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CHEM 421 Mass SpectrometryW 2C 0.5

Principles involved in the use of electric and magnetic fields for mass analysis. lonization methods. Applications of mass spectrometric analysis to the identification and quantitation of chemical compounds.

Prereq: CHEM 264, or permission of instructor

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CHEM 422 Thermal and Electrical Analytical MethodsF 2C 0.5

Techniques and fundamental principles

of thermal and electroanalytical methods.

Prereq: CHEM 221 or permission of instructor

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CHEM 425A Special Topics in Analytical Chemistry-Z F,W,S 2C 0.5

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CHEM 432 Metabolism 2F 2C 0.5

Properties and metabolism of porphyrins, purines, pyrimidines and biogenic amines. Structure-function relationships of enzymes. Control and transport mechanisms.

Prereq: CHEM 333

Coreq: CHEM 332

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CHEM 433 Advanced BiochemistryW 2C 0.5

Oxidative phosphorylation. Vision. Meval-

onic acid pathways. Serine proteases.

Prostaglandins. Salt balance. Respiration. Prereq: CHEM 333

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CHEM 434 Special Topics in BiochemistryW 2C 0.5

Special topics in biochemistry with applications. Areas covered in recent years include biochemistry of methaneproducing bacteria; mechanism of action of antibiotics, antiviral agents and vitamins.

Prereq: CHEM 333

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CHEM 435 Bioorganic MechanismsF 2C 0.5

Modern techniques of biosynthetic

studies. Enzyme reaction mechanisms. Prereq: CHEM 237 and one of 368.

366

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CHEM 452 Colloids, Liquid Crystals and Bilayer Chemistry ,F 2C 0.5

The colloidal size range, the importance of the interface, classical studies on Brownian motion, light scattering, the micelle formation of detergents in water and solubilisation. Phase diagrams of soaps and lipids and their study by X-ray diffraction and NMR. The biological membrane as an entity of colloidal size. The related spectroscopy, microscopy, etc. of lyotropic liquid crystals and bilayers.

Prereq: CHEM 255

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CHEM 453 Polymer Properties andW 2C 0.5

Polymerization

Copolymerization, ionic and coordinate

polymerizations, introduction to polymer

reaction engineering, mechanical proper-

ties of polymers, polymer mixtures. Prereq: CHEM 353 or equivalent Antireq: CH E 542

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CHEM 454 Surface ChemistryF 2C 0.5

An introduction to the physical chemistry of surfaces. Qualitative’and quantitative descriptions of surfaces and interfaces and the development of relevant techniques and theories. Application to surface tension, spreading, wetting, adsorption, and other interfacial phenomena.

Prereq: CHEM 358

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CHEM 455 ElectrochemistryF 3C 0.5

Electrolytic conductance and transport, thermodynamics of electrolytic cells. Reversible and irreversible electrode processes, metallic corrosion. Study of selected industrial electrochemical processes.

Prereq: CHEM 254 or 356

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CHEM 456 CatalysisW 2C 0.5

An introduction to heterogeneous cata-

lysis. Examination of the physical mani-

festations of catalysis and the develop-

ment of experimental techniques and

theoretical methods for the measurement

and elucidation of catalytic phenomena. Prereq: CHEM 255

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CHEM 457 Experimental Aspects of Polymer ScienceW 1C6L 0.5

Selected experiments to illustrate polymerization, polymer properties and fabrication processes.

Prereq: CHEM 353 or equivalent

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CHEM 458 Quantum ChemistryF 2C 0.5

The nature of electronic structure and chemical bonding in H,* and other simple molecules and its implications for theories of chemical reactions.

Prereq: CHEM 355

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CHEM 464 Spectroscopy in Organic ChemistryF 2C 0.5

Elucidation and identification of organic structures by contemporary spectroscopic techniques.

Prereq: CHEM 265

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CHEM 465 Special Topics in Organic ChemistryW 2C 0.5

Topics will be selected from photochemistry, organometallics, synthesis, heterocyclics, natural products, molecular rearrangements. (May be taken in third and fourth year as 465A and 465B provided topics are different).

Prereq/Coreq: CHEM 368

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CHEM 492A Advanced LaboratoryF QL 0.75

Laboratory work on a senior year research project. See CHEM 492 co-ordinator for descriptive booklet and details.

For Honours students only

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CHEM 492B W QL 0.75

A continuation of CHEM 492.

No credit or grade is given for the first term course unless the two term sequence, CHEM 492A/B, is completed.

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CHEM 495A Research Project 3F 18L 1.5

Only for students in the Honours Chemistry (Thesis Option) program.

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CHEM 495B Research Project 4W 18L 1.5

Only for students in the Honours Chemistry (Thesis Option) program.

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CHEM 496A Independent Study in the Defined Field of Study-E F,W,S R 0.5

A - Analytical Chemistry

B - Biochemistry

C - Inorganic Chemistry

D - Organic Chemistry

E - Physical Chemistry

Open to students in the Honours Chemistry (Thesis Option) program only.

Department of Civil Engineering

Professor, Chairman of the Department R.C.G. Haas, BSc, MSc (Alberta), PhD (Waterloo), PEng

Professor, Dean of the Faculty of

Engineering

W.C. Lennox, BASc, MSc (Waterloo), PhD (Lehigh), PEng

Professor, Associate Chairman Graduate

Studies

J.F. Sykes, BASc, MASc, PhD (Waterloo), PEng

Associate Professor, Associate

Chairman, Undergraduate Studies

B. LeLievre, BEng (West Australia), MASc, PhD (Waterloo), PEng

Professors Emeritus

H.H.E. Leipholz,’ Dip! Eng, Dr Ing, Docent Habil (Stuttgart), DEng (Waterloo), DEng (Carleton), PEng, FRSC, Recipient of the Distinguished Teacher Award

J.T. Pindera, Dr. of Tech Sciences (Warsaw), Docent Habil (Cracow), PEng

Professors

S.T. Ariaratnam, BSc (Eng) (Ceylon), MSc (London), PhD (Cambridge)

E.F.P. Burnett, BSc (Capetown), DIC, MS, PhD (London), PEng

M.Z. Cohn, CSc (Bucharest), PEng

M.B. Dusseault,> BSc, PhD (Alberta), PEng

G.J. Farquhar,? BASc (Waterloo), PhD (Wisconsin), PEng, Recipient of the Distinguished Teacher Award

GML. Gladwell? BSc, PhD, DSc (London)

Course Descriptions 16:27 Chemistry

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