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Chemical Engineering (CHE)

81 courses in the 1968–69 Undergraduate Calendar, read from the scanned original. The text comes from OCR, so check the scanned page before relying on a detail.

Notes

Faculty listed in 1968–69

D.S. Scott, B.Sc., M.Sc. (Alberta), Ph.D. (Illinois), Professor Chairman of the Department T.L. Batke, B.A.Sc., M.A.Sc., Ph.D. (Toronto), Professor Vice-President, University Development D.H. Baker, Jr. M.Sc. (Arizona) Professor F.A.L. Dullien, Dipl. Ing. (Budapest Technical University), Professor M.A.Sc., Ph.D. (British Columbia) P.M. Reilly, B.A.Sc., (Toronto), D.I.C., Ph.D. (London), F.S.S. Professor G.A. Truner, B.Sc.(London), Ph.D. (Manchester) Professor B.M.E. van der Hoff, Ing. (Amsterdam), Ir. (Delft) Professor A.H. Heatley, B.A.Sc., M.A., Ph.D. (Toronto) Professor Emeritus L.E. Bodnar, Ph.D. (McMaster) Associate Professor

J.J. Byerlye, B.A.Sc., M.A.Sc. (Toronto), Ph.D. (British Columbia) Associate Professor K. Enns, B.A.Sc., LL.B., M.A.Sc. (Toronto}, Ph.D. {Toronto} Associate Professor

T.Z. Fahidy, B.Sc. (Hon.}, M.Sc. (Queen’s) Ph.D. (Illinois) Associate Professor J.D. Ford, B.A.Sc., M.A.Sc. {Toronto} Associate Professor C.E. Gall, B.A.Sc. (Toronto), M.Sc. (Queen's) Associate Professor

R.Y-M. Huang, B.Sc. (National Taiwan University), M.A.Sc., Ph.D. (Toronto)

Associate Professor D.C.T. Pie, B.Eng. {McGill}, M.Sc. (Queen's), Ph.D. (McGill) Associate Professor E. Rhodes, B.Sc. Tech., M.Sc.Tech., Ph.D. (Manchester) Associate Professor P.L. Silveston, B.S., M.S. (Massachusets Inst. of Tech). Dr.Ing. (Munich)

Associate Professor M. Moo Young, B.Sc. {London}, M.A.Sc. (Toronto}, Ph.D. (London)

Associate Professor C.M. Burns, B.A.Sc., M.A.Sc. (Toronto), Ph.D. (Brooklyn Polytechnic Inst.)

Assistant Professor K.S. Chang, B.S. (Hanyang Inst. Tech., Seoul}, M.Sc., Ph.D. (Northwestern)

Assistant Professor

G.D. Fulford, B.Sc., Ph.D. (Birmingham) Assistant Professor R.R. Hudgins, B.A.Sc., M.A.Sc. (Toronto), Ph.D. (Princeton) Assistant Professor W.H. Ray, B.A., B.S. (Ch.E.) (Rice), Ph.D. (Minnesota) Assistant Professor J.M. Scharer, B.Sc., Ph.D. (Pennsylvania) Assistant Professor

Undergraduate Course Descriptions

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CHE 10 Chemical Process Principles I

Units and dimensions. Stoichiometry—mass balances, simple energy balances, equilibrium. Free hand sketching and blue print reading, concepts of synthesis. Introductory chemical engineering laboratories

Including experiments in measurement.

2 lectures, 3 hours lab.—two terms.

Department of Chemical Engineering

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CHE 12 Chemical Process Principles HI. Equilibrium between phases; the equilibrium stage concept

Cascades of stages with and without reflux; examples of their analysis when used to separate components by distillation, extraction, absorption and leaching. Small solids; their description in quantitive terms; separation by differences of size and density. Thickening.

3 lectures, 2 hours problems, alternative weeks.

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CHE 16 Inorganic Chemistry

Introduction to the periodic classification and electronic structure of the elements.

Prerequisite: Chem. II.

3 lectures, one term.

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CHE 17 Applied Mathematics I

Laplace Transforms, introduction to vector analysis and matrix algebra, formulation of ordinary and partial differential equations describing physical systems.

3 lectures, one term.

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CHE 18 Applied Mathematics II

Statistical frequency distributions. Tests of significance. Correlations. Curve fitting. Sampling theory. Applications: small particles, dispersive waves, errors, design of experiments.

2 lectures, 3 hours problems, alternate weeks.

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CHE 22 Transport Processes II

Introduction to heat transfer. Steady and transient heat conduction. Laminar and turbulent convection, the laminar boundary layer, momentum-heat transfer analogies. Heat transfer with change of phase. Radiant heat transfer.

Prerequisite: G.E. 32.

3 lectures, oné term.

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CHE 23 Transport Processes HII. Diffusion and mass transfer by molecular and turbulent action

Interrelationship of momentum, energy and mass transport phenomena. The performance of apparatus for carrying out diffusional operations.

Prerequisite: Ch.E. 22.

3 lectures, one term.

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CHE 31 Physical-Chemical Principles I

Gases, first law of thermodynamics, thermochemistry, second law of thermodynamics, one component systems, solutions, properties of dilute solutions, phase equilibria and the phase rule, kinetic theory and macromolecules.

3 lectures, one term.

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CHE 32 Thermodynamics I

Principles of thermodynamics. Criteria of physical and chemical equilibria, Pressure-volume-temperature relations of fluids. Energy conversion. Prerequisites: ChE 11, ChE 31.

3 lectures, 2 hours problems alternate weeks, one term.

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CHE 33 Thermodynamics II

Flow processes. Properties of real solutions. Vapor-liquid equilibria. Equilibria in chemical reactions.

Prerequisite: ChE 32.

3 lectures, one term.

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CHE 36 Physical-Chemical Laboratory

A laboratory to demonstrate physical chemical principles and techniques of physical measurement. Concurrently with ChE 31. 3 hours laboratory, one term.

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CHE 41 Reaction Kinetics 1

Introduction to kinetics and mechanism of elementary chemical processes in homogeneous systems; reversible, consecutive and simultaneous reactions, interpretation of kinetic data, homcgeneous catalysis, chain reactions. Prerequisites: ChE 12. ChE 31.

3 lectures, one term.

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CHE 42 Reaction Kinetics II

Use of material balances: design of isothermal flow, stirred tank and batch reactors by analytical, graphical and numerical techniques; non isothermal design for simple cases.

Prerequisite: ChE 41.

3 lectures, one term.

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CHE 51 Process Dynamics and Control I

Block and signal flow diagrams, proportionalintegral-derivative controllers, frequency response techniques, analytical and graphical stability criteria, Introduction to modern control theory.

Prerequisite: Math. 31, Ch.E. 22

3 lectures, one term.

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CHE 61 Engineering Economics

Mathematics of annuities, mortgages, bonds, and small loans. Cost accounting, including direct costing, depreciation, taxes and financial statements. Estimation of sales and capital and operating costs of a new process or product. Study of criteria for the appraisal of capital expenditures. Introduction to the Critical Path Method. Introduction to Linear Programming.

3 lectures, one term.

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CHE 62 Process System Design

The undergraduate curriculum is co-ordinated and brought together to accomplish the basic objective of the process engineer, the design of an integrated chemical process.

Prerequisites: All Chemical Engineering required courses.

)2 lectures, 3 hours problems, one term.

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CHE 71 Chemical Engineering Laboratory I

Experiments in the application of physical and chemical principles to engineering analysis, phase equilibrium, fluid flow and heat transfer.

Prerequisites: ChE 12, ChE 21.

4 hours laboratory, one term.

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CHE 72 Chemical Engineering Laboratory II

Experimental studies with pilot plant equipment in the representative unit operations: evaporation, distillation, absorption, extraction, drying, humidification and reactors.

Prerequisites: ChE 13, ChE 71.

6 hours laboratory, one term.

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CHE 80 Introduction of Polymer Science

Basic concepts of polymer chemistry, classification of polymers, introductory physical chemistry of polymers, organic chemistry of polymerization reactions, reactions of polymers, naturally occurring polymers.

3 lectures, one term.

Department of Chemical Engineering

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CHE 81 Physical Chemistry of Polymers

Polymer solutions, molecular characterization of polymers, molecular weight distributions, morphology and crystallinity in polymers, reaction kinetics and mechanisms of addition and condensation polymerization, polymer structure and physical properties.

Prerequisite: Ch.E. 80.

3 lectures, one term.

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CHE 82 Polymer Processing

Polymer rheology and processing, engineering aspects of viscoelasticity. Compounding, plasticization, stabilization and reinforcement of polymers. Fabrication processes: compression and injection moulding, calendaring, extrusion and vacuum forming. Physical test methods. Engineering design with polymers.

3 lectures, one term.

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CHE 85 Chemical Metallurgy

Introduction to metallurgical processes, ore dressing, calcining, roasting, leaching, reduction, precipitation and refining. Discussion and application of physico-chemical principles as related to pyrometallurgical and hydrometallurgical reactions. Technology of base metal production.

3 lectures, one term.

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CHE 95 Seminar

Study and presentation of material in recent literature. 1 hour, one term.

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CHE 98 Research and Design Project I

3 hours, one term.

99, Research and Design Project II. Prerequisite: ChE 98. 6 hours, one term.

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CHE 535 Estimation of Properties of Gases and Liquids The activities of the chemical or process engineer have often been referred to as “‘molecular engineering”

One of his basic needs is reliable quantitative data on the physical, chemical and thermodynamic properties of pure substances and mixtures. - This course is intended to familiarize the student with the most up-to-date methods available for the estimation of certain of the more important properties of gases and liquids in cases where experimental values are not to be found. Prediction is usually based on correlations of a form suggested in part by theory, with empirical constants based on experimental data. Prerequisite: ChE 32.

3 lectures, one term.

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CHE 543 Reaction Kinetics III

Kinetics of heterogeneous and catalytic reactions; design and scale up of heterogeneous reactors.

Prerequisite: ChE 42.

3 lectures, one term.

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CHE 552 Process Dynamics and Control II

Analog computation, time domain analysis, control of complex chemical systems.

Prerequisite: Ch.E. 51

3 lectures, one term.

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CHE 554 Chemical Engineering Analysis

More rigorous treatment of vector and matrix algebra, integral transform techniques for solution of equations describing physical systems, applications to chemical processes.

Prerequisite: Permission of Instructor

3 lectures, one term.

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CHE 587 Metallurgy of Iron and Steel

A study of Iron and Steel making from a Physical- Chemical approach using the interrelationships of physics and chemistry to understand structural, thermodynamic and kinetic factors. Some of the material to be included—Physical Nature of Solution, Metal-Slag Reactions, Slag Theory, Non-Equilibrium Conditions, Steel Making Processes, Carbon-Oxygen reactions, Impurity problems and Reaction of the Blast Furnace.

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CHE 590 Biochemical Engineering Processes

Introduction to the application of Chemical Engineering principles to the processing of materials of biological character or origin. Methods of solving problems imposed by biological character or origin. Methods of solving problems imposed by biological and related factors on process design in the manufacturing industries. Food and beverage. Enzymes, Antibiotics, Vitamins, Effluent disposal.

3 lectures, one term.

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CHE 591 Industrial Microbiology

Introductory study of microorganisms of industrial significance. Growth, metabolism and stability relevant to engineering design. Quality control in biotechnology.

3 lectures, one term.

Graduate Course Descriptions

The Department of Chemical Engineering offers courses of study leading to the degrees of Master of Applied Science and Docotor of Philosophy. The Master of Applied Science programme may be followed in either one of two directions: a “professional” option, which requires course work and an engineering report; and a “‘research” option, which requires less course work, and the completion of a research project. The first of these is intended to give a fuller understanding of fundamentals and greater mastery of the application of these principles to the solution of complex realistic problems. The second option offers training in fundamentals and in research methods, and is excellent preparation for those wishing to proceed to the Ph.D. degree, or for those whose primary interest is a career in research.

In addition to general and specialized graduate courses for research students, the Department offers a number of courses each year designed to be particularly suitable for the professional option in the M.A.Sc. programme. Graduate course requirements are measured in “units.” A course lasting one semester may be considered to be one unit. Normally, four units per semester are considered a full load, but if more than six hours/week of other work is also being done, a student may be required to carry fewer units.

Department of Chemical Engineering

Either option in the M.A.Sc. programme may also be carried out on a part-time or full-time co-operative basis. The professional option is particularly designed to meet the needs of a co-operative programme.

The Master’s Degree Programme The professional option requires a total of eight units of course work, in addition to the submission of an acceptable engineering report. Normally, at least five units of work will be chosen from courses offered by the Chemical Engineering Department four units of which must be Ch.E. 600, 642, 650, and 672. Other courses may be chosen either from outside Departments or from other Chemical Engineering courses. The engineering report will have a nominal value of one to two units, and represents evidence that the student is capable of obtaining and presenting a satisfactory solution to an original engineering problem of some complexity. The research option requires a total of four units of course work at the graduate level, in addition to the submission of a thesis reporting the results of original research. The courses to be taken will be selected in consultation with the student’s research advisor.

The minum period for a full-time student to complete either option is 8 months, and the average time required will be one calendar year.

The PhD. Programme The Ph.D. degree is awarded primarily for the successful performance of original research of high calibre. The general requirements are described in the section dealing with Graduate Studies, and particular requirements are available from the Department of Chemical Engineering on request. The courses to be taken by a student in the Ph.D. programme will be determined by his Committee, and will normally consist of about four to eight units of work, in addition to the research thesis.

A student in the Ph.D. programme is not accepted as a candidate for the Ph.D. degree by this Department until he has presented and successfully defended to his Committee a proposal for research.

Research Activities

Graduate research may be pursured in a number of major areas of investigation, which are listed below. In addition to work in these fields, a wide variety of research is carried out in less intensively developed areas.

Major areas of research interest are.

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CHE 1 Biochemical Engineering—Heat transfer, mass transfer, and fluid flow in biological processes of industrial interest; chemical engineering design of fermentation, food processing, and waste treatment facilities

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CHE 2 Chemical Kinetics and Catalysis—Investigation of reaction rates in inorganic and organic systems, selectivity studies in catalysis, homogeneous catalysis, heat and mass transfer in heterogeneous systems, chemical reaction engineering

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CHE 3 Process Control and Dynamics—Simulation, process control theory, applications of control theory to actual chemical systems, computer control, process analysis and dynamics, operations research, optimal design, control of chemical plants

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CHE 4 Transport Phenomena—Heat and mass transfer in gas-solid, gas-liquid, liquidliquid and other multiphase systems

Concurrent flow transport processes, boundary layer theory, turbulence at mobile interfaces, condensing vapor heat transfer, microwave heating, frequency response methods, diffusion studies, etc.

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CHE 5 Polymer Science—Diffusion through modified membranes, radiation graft polymerization, emulsion polymerization, stress relationships in elastomers, physical properties of polymers, etc

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CHE 6 Chemical Metallurgy—Hydrometallurgical processes, solid state reactions, mineral beneficiation, powder and solids handling technology pelletization, reactivity of solids

Details of Graduate Courses All courses are one term, and except for those listed under “Special Topics,” are given every year.

The following four courses are intended to serve as advanced core courses giving fairly broad coverage in a field. It is expected that all graduate students will normally take one or more of these four before proceeding to more specialized graduate course work.

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CHE 600 Theory and Applications of Transport Phenomenon

Evaluation of molecular transport properties, Equations of mass heat and momentum transport, boundary layer and turbulance theory, application to analysis of flow systems, heat transfer equipment, and mass transfer operations.

3 lectures, one term.

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CHE 642 Chemical Thermodynamics, Kinetics, and Reactor Design

Review of laws of thermodynamics, Gibbs equation, thermochemistry, chemical reaction equilibrium, kinetics of homogeneous and heterogeneous systems, techniques for kinetic parameter determination, problems in design, optimization, and control of complex reactors.

3 lectures, one term.

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CHE 650 Process Optimization

An engineering treatment of the popular forms of the calculus of variations: maximum principle, dynamic programming. Optimization of staged systems. Optimum seeking methods. Optimization of complex plants by decomposition. Applications to process design and control.

3 lectures, one term.

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CHE 672 Advanced Mathematics in Chemical Engineering

Review of fundamenta] concepts and methods of mathematical analysis with applications in Chemical Engineering. Topics covered will be selected from Advanced Calculus, Vector Analysis, Tensor Analysis, Matrix Algebra and Calculus, Ordinary and Partial Differential equations, numerical techniques. The emphasis will be placed on the general usefulness of the methods in a wide variety of research and design problems.

Prerequisite: Permission of Instructor.

3 lectures, one term.

Department of Chemical Engineering

The courses below are intended mainly for students pursuing a research project, but are open to those in the professional course with the consent of the instructor and of the students’ advisors. The courses described below are of a broader scope than those listed as Special Topics in Groups A, B or C.

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CHE 602 Processing and Properties of Solids. Particle and pore size analysis, conveying of

solids in fluids, heat and mass transfer in beds of solids, behavious of dense beds of fine solids.

3 lectures, one term.

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CHE 624 Liquid-fluid Transfer Processes

An advanced survey of gas-liquid and liquid-liquid heat and mass transfer operations in flowing systems. Special emphasis will be placed on one or more of the following topics: transfer mechanisms at fluid-liquid interfaces, drop and bubble phenomena, cascade theory of separation processes, transfer processes in two-phase tube flow, packed column behaviour, mass and heat transfer during mixing, boiling and condensation phenomena.

3 lectures, one term.

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CHE 634 Statistical Theory of Matter

Introduction to statistical methods, statistical description of systems of particles, statistical thermodynamics, techniques and results of statistical mechanics with application, kinetic theory of transport, irreversible processes.

3 lectures, one term.

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CHE 640 Chemical Reactors for Homogeneous Systems

Structure of stoichiometry, determination of kinetic parameters, polymerization kinetics, optimal design reactor stability, optimal control, mixing and residence time distributions.

3 lectures, one term.

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CHE 641 Chemical Reactors for Heterogeneous Systems

Structure and preparation of solid catalysts, physical properties, nature of active surfaces and activated adsorption, selection of catalysts, heat and mass transfer in packed and fluidized bed reactors, design of heterogeneous catalytic and non-catalytic reactors.

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CHE 644 Advanced Chemical Kinetics

Kinetics of homogeneous reactions: Gas phase reactions and theories of reaction, liquid phase reactions including ionic reaction and acid-base catalysis. Kinetics of heterogeneous catalysis: adsorption, theories of adsorption and catalysis; modelling complex mechanisms; detailed examination of a few systems.

3 lectures, one term.

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CHE 673 Advanced Mathematics in Engineering Research

Generalizes and extends the techniques of Ch.E. 672.

Prerequisite: Ch.E. 672.

3 lectures, one term.

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CHE 680 Principles of Polymer Science

Introduction to the physical chemistry of high polymers, principles of polymer synthesis, mechanisms and kinetics of polymerization reactions, copolymerization theory, polymerization in homogeneous and _ heterogeneous systems, chemical reactions of polymers. Theory and experimental methods for the molecular characterization of polymers.

3 lectures, one term.

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CHE 681 Polymer Synthesis and Characterization

The synthesis of polymers of theoretical and industrial importance by ionic, free radical and condensation methods. Commercial and laboratory syntheses of monomers. Copolymerization. Crosslinking reactions. Polymerization kinetics and mechanisms. Stereoregulation of polymer structure. Correlation of polymer tacticity, branching and molecular weight distribution with the polymerization mechanism. Recent methods of polymer characterization.

Prerequisite: Ch.E. 680

3 lectures, one term.

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CHE 683 Physical Properties of Polymers

Molecular and morphological structure of high polymers, molecular interpretation of mechanical properties of solid polymers, phenomenological viscoelasticity, confirmation of polymeric chains. Transition phenomena, thermodynamics of polymers and the kinetic theory of rubber elasticity. Rheology of polymer melts.

Prerequisite: Ch.E. 690.

3 lectures, one term.

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CHE 684 Advanced Polymer Science

Selected advanced topics in the thermodynamics of polymer solutions, kinetics of polymerization, kinetics and thermodynamics of crystallization and melting, polymer degradation, transport phenomena in polymers. Prerequisite: Ch.E. 682 and 683.

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CHE 686 Hydrometallurgy

General discussion of hydrometallurgical systems; ionic processes in aqueous solutions, thermodynamics and kinetics of leaching, precipitation, and reduction processes; design problems encountered in hydrometallurgical operations.

3 lectures, one term.

Co-operative Chemical Engineering student on work term assignment

Department of Chemical Engineering

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CHE 687 Theoretical Chemical Metallurgy

The application of physicochemical principles to chemical metallurgy; thermodynamic equilibria of heterogeneous processes, electrolytic and electrode reactions, theory of rate processes and their application to process metallurgy.

3 lectures, one term.

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CHE 690 Biochemical Engineering Operations I

Mass-transfer, and mixing in non-Newtonian systems. Design of fermenters. Sterilization Techniques. Air and nutrient media supplies. Extraction and separation methods.

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CHE 691 Biochemical Engineering Operations II

Mass-transfer and heat-transfer with biochemical reactions. Design and control of continuous-flow processes for biological

systems. Exploration of new methods of producing materials for food and medicinal purposes and of treating effluents.

Special Topics

Group A—(Topics in Transport Theory)

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CHE 705 Particle-Fluid Dynamics

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CHE 707 Non -Newtonian Flow

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CHE 715 Radiant Heat Transfer

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CHE 716 Heat Transfer in Two Phase Systems

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CHE 724 Use of Transient and Frequency Response to measure Physical Quantities

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CHE 725 Gas-Liquid Mass Transfer Processes

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CHE 726 Dissolution and Crystallization

727. lon Exchange

Group B—(Topics in Thermodynamics and Chemical Kinetics)

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CHE 735 Advanced Thermodynamics

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CHE 736 Surface Chemistry

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CHE 745 Physical Processes in Heterogeneous Catalysis

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CHE 746 Kinetics of Consecutive and Chain Reactions

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CHE 747 Kinetics of Biological Systems

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CHE 748 Residence Time Distributions, Reactor Flow Models and Reactor Stability

Group C—(Topics in Control Theory and Applied Mathematics)

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CHE 754 Mathematical modeling of Chemical Processes

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CHE 755 Analysis of Non-linear Processes

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CHE 756 Control of Complex Processes

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CHE 757 Optimization Problems in Chemical Processes

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CHE 765 Basic Statistics in Engineering

766, Topics in Advanced Process Control

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CHE 767 Special Topics in Analysis of Processes

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CHE 768 Advanced Statistics in Engineering

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CHE 797 Engineering Report

Every professional student is expected to complete the solution of, and prepare a report, on a major problem in process design or evaluation. Problems may be suggested by the student or by the staff.

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CHE 801 Oral Examination of the Thesis for the Ph.D

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CHE 802 Graduate Seminar

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CHE 803 Research Proposal for Ph.D

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CHE 804 Russian or German language proficiency for Ph.D

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