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Chemical Engineering (CHE)

39 courses in the 1971–72 Undergraduate Calendar, read from the scanned original. The text comes from OCR, so check the scanned page before relying on a detail.

Notes

Department of Chemical Engineering

Faculty listed in 1971–72

Professor and Chairman of K.F. O’Driscoll, B.Ch.E. (Pratt Inst.), M.S., Ph.D. (Princeton).

T.L. Batke, B.A.Sc., Ph.D. (Toronto). (On leave of absence)

F.A.L. Dullien, Dipl Ing. (Budapest Technical University), M.A.Sc., Ph.D. (U.B.C).

D.C.T. Pei, BEng. (McGill), M.Sc. (Queen's), Ph.D. (McGill).

P.M. Reilly, B.A.Sc. (Toronto), D.L.C., Ph.D. (London), FSS. DS. Scott, B.Sc., M.Sc. (Alberta), Ph.D. (Illinois).

P.L. Silveston, BS, M.S. (M.LT.), Dr.Ing. (Munich)

Faculty listed in 1971–72

D.R. Spink, B.S. (Mich.), M.S. (Rochester), Ph.D. (Iowa State) G.A. Turner, B.Sc. (London), Ph.D. (Manchester).

B.M.E. van der Hoff, Ing. (Amsterdam), Ir. (Delf).

Faculty listed in 1971–72

A.H. Heatley, B.A.Sc., M.A., Ph.D. (Toronto).

L.E. Bodnar, B.A., M.A. (Sask.), Ph.D. (McMaster).

J.J. Byerley, B.A.Sc., M.A.Se. (Toronto), Ph.D. (U.B.C.).

K.S. Chang B.S. (Hanyang Inst. Tech., Seoul), M.Sc., Ph.D. (Northwestern).

K. Enns, B.A4.Sc., LL.B., M.A.Sc., Ph.D. (Toronto).

T.Z. Fahidy, B.Sc, M.Sc. (Queen’s), Ph.D. (Illinois).

J.D. Ford, B.Eng. (McGill), M.A. Sc., Ph.D. (Toronto)

C.E. Gall, B.A.Sc. (Toronto), M.Sc. (Queen's), Ph.D. (Minn.). R.Y-M. Huang, B.Sc. (National Taiwan University), M.A.Sc., Ph.D. (Toronto)

R.R. Hudgins, B.A.Sc., M.A.Sc. (Toronto), Ph.D. (Princeton).

E. Rhodes, B.Sc. Tech., M.Sc. Tech., Ph.D. (Manchester).

J.R. Wynnyckyj, BEng. (McGill), M.A.Sc., Ph.D. (Toronto).

M. Moo-Young, B.Sc. (London), M.A.Sc. (Toronto), Ph.D. (London). C.M. Burns, B.4.Sc., M.A.Sc. (Toronto), Ph.D. (Brooklyn Polytechnic Inst.)

LF. Macdonald, B.Eng. (N.S.T.C.), Ph.D. (Wisconsin).

Faculty listed in 1971–72

G.L. Rempel, B.Sc., Ph.D. (U.B.C.).

C.W. Robinson, B.A.Sc. (U.B.C.), Ph.D. (U.C.,, Berkeley).

J.M. Scharer, B.Sc., Ph.D. (Pennsylvania).

Undergraduate Course Descriptions

Units and dimensions. Stoichiometry: simple mass and energy balances. Free hand sketching and blue-print reading. Introductory chemical engineering laboratories including experiments in measurement.

2 lectures, 2 hours lab., 1 hour tutorial, two terms.

The equilibrium stage concept. Cascades of stages with and without reflux; example of separation by distillation, extraction, adsorption and leaching. Small solids: their description, separation and collection. Prerequisite: Ch. E. 32.

3 lectures, 2 hours problems (alternate weeks), one term.

Introduction to the periodic classification and electronic structure of the

17 Applied Mathematics 1

18 Applied Mathematics 2

21 Transport Processes 1 (Fluid Mechanics)

22 Transport Processes 2 (Heat Transfer)

23 Transport Processes 3 (Mass Transfer)

31 Physical Chemistry 1

32 Physical Chemistry 2 33 Chemical Engineering Thermodynamics

35 Electrochemistry

36 Physical-Chemical Laboratory

Department of Chemical Engineering 195

3 lectures, one term.

Laplace transforms, introduction to vector analysis and matrix algebra, formulation of ordinary and partial differential equations describing physical systems.

3 lectures, one term.

Statistical frequency distributions. Tests of significance. Correlations. Curve fitting. Sampling theory. Applications: small particles, dispersive waves, errors, design of experiments.

2 lectures, 3 hours problems (alternate weeks), one ter.

Physical properties of fluids and fundamental concepts of fluid flow. Conservation laws for mass, momentum, energy, and entropy. Applications to a variety of engineering problems.

3 lectures, 3 hours laboratory, one term.

Introduction to heat transfer. Steady and transient heat conduction. Laminar and turbulent convection, the laminar boundary layer, , momentum-heat transfer analogies. Heat transfer with change of phase. Radiant heat transfer.

Prerequisite: Ch.E. 21.

3 lectures, one term.

Diffusion and mass transfer by molecular and turbulent action. Interrelationship of momentum, energy and mass transport phenomena. The performance of apparatus for carrying out diffusional operations. Prerequisite: Ch.E. 22

3 lectures, one term.

Principles of thermodynamics. One component systems, pure phase (gases, liquids and crystals), phase equilibria. 3 lectures, one term.

Solutions. Equilibria in multicomponent homogeneous and heterogeneous systems. Elements of kinetic theory of gases.

Prerequisite: ChE. 31.

3 lectures, 2 hours problems (alternate weeks), one term.

Technical thermodynamic power plant cycles, refrigeration cycles, high pressure equilibria, analysis of flow processes.

Prerequisite: Ch.E. 32.

3 lectures, one term.

Electrolytic conductance and transport. Ionic equilibria. Reversible electrode potentials. Irreversible electrode processes and electrode kinetics. Theoretical and practical aspects of corrosion.

3 lectures, one term.

A laboratory to demonstrate common physico-chemical principles and techniques of physical measurements. Training in technical report writing is included. Experiments on viscosity of gases and liquids, chemical kinetics, adsorption, homogeneous and heterogeneous catalysis, thermochemistry, phase equilibria, diffusion, determination of molecular weight of polymers and complex formation.

3 hours laboratory, one term.

41 Reaction Kinetics 1

42 Reaction Kinetics 2

| Process Dynamics and Control

61 Engineering Economics 62 Process Systems Design 71 Chemical Engineering Laboratory 1

72 Chemical Engineering Laboratory 2

73 Process Contro] Laboratory

80 Introduction to Polymer Science

81 Physical Chemistry of Polymers

Department of Chemical Engineering

Introduction to kinetics and mechanism of elementary chemical processes in homogeneous systems: reversible, consecutive and simultaneous reactions, interpretation of kinetic data, homogeneous catalysis, chain reactions.

Prerequisite: Ch.E. 32

3 lectures, one term.

Use of material balances: design of isothermal flow stirred tank and batch reactors by analytical, graphical and numerical techniques; non-isothermal design for simple cases.

Prerequisite: Ch.E. 41

3 lectures, one term.

Block and signal flow diagrams, proportional-integral-derivative controllers, frequency response techniques, analytical and graphical stability criteria. Introduction to modern control theory. Prerequisites: Math. 31, Ch.E. 22.

3 lectures, one term..

The study of the economic processes involved in the chemical industry; this will include process design development, cost estimation, profitablity and optimum design with an introduction to linear programming

3 lectures, one term.

The undergraduate curriculum is co-ordinated and brought together to accomplish the basic objective of the process engineer, the design of an integrated process.

2 lectures, 3 hours problems, one term.

Experiments in the application of physical and chemical principles to engineering analysis, phase equilibrium, fluid flow and heat transfer. Prerequisites: Ch.E. 12, Ch.E. 21

4 hours laboratory, one term.

Experimental studies with pilot plant equipment in the representative unit operations: evaporation, distillation, absorption, extraction, drying, humidification and reactors.

Prerequisites: Ch.E. 71

6 hours laboratory, one term.

Experiments on process dynamics and control and analog simulation of chemical processes. Time constant, step and frequency response, controller settings, and cascade control of thermal, liquid level, and reaction systems.

Prerequisite: Ch.E. 51.

4 hours laboratory, one term.

Basic concepts of polymer chemistry, classification of polymers, introductory physical chemistry of polymers, organic chemistry of polymerization reactions, reactions of polymers, naturally occuring polymers. : 3 lectures, one term.

Polymer solutions, molecular characterization of polymers, molecular weight distributions, morphology and crystallinity in polymers, reaction

82 Polymer Technology

85 Introduction to Extractive Metallurgy

86 Metallurgical Chemistry

87 Principles of High Temperature Extractive Metallurgy

95 Seminar

98 Research and Design Project 1

99 Research and Design Project 2

Department of Chemical Engineering 197

Prerequisite: Ch.E. 80. 3 lectures, one term.

Technically important polymers, thermo-viscoelastic properties, dimensional and chemical stability, polymer processing, rheology, compounding and mixing, thermo-forming processes, film formation, fibre forming, chemistry of thermo-setting and curing reactions. Prerequisite: ChE. 81. 3 lectures, one term.

The application of principles of thermodynamics and kinetics to metallurgical processes. Pyrometallurgy, electrometallurgy and hydrometallurgy are covered. Extraction of metals is analysed from the point of view of abundance, ease of extraction and useful properties of the metal.The chemical nature of ores, as well as important intermediates. 3 lectures, one term.

Ionic equilibria. Thermodynamics and kinetics of reactions in solution. Bonding, stability and stereochemistry of coordination compounds and mechanisms of their reactions. Introductory hydrometallurgy; corrosion and homogeneous catalysis. 3 lectures, one term.

Detailed study of the underlying principles of several metallurgical processes of importance in Canada. Subjects covered include kinetics and mechanisms of roasting and reduction reactions, industrial roasting, blast furnace and electric furnace reduction: nature of melts and slags, slag metal reactions; converting, refining and fuse salt electrolysis. Problems being worked on in various extractive metallurgy research laboratories will be reviewed. 3 lectures, one term.

Study and presentation of material in recent literature, or from industrial experience. I hour, one term.

Equivalent to one course, one term.

Prerequisite: Ch.E. 98. Equivalent to two courses, one term.

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CHE 535 Physico-chemical Properties of Gases and Liquids

The most up-to-date methods available for the estimation of the more important physico-chemical properties of gases and liquids in cases where experimental values are not to be found. Prediction is usually based on correlations of a form suggested in part by theory, with empirical constants based on experimental data. Prerequisite: Ch.E. 32 3 lectures, one term.

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CHE 543 Reactor Design

‘Kinetics of heterogeneous and catalytic reactions; reactor design and scale-up procedures. Prerequisite: Ch.E. 42. 3 lectures, one term.

Department of Chemical Engineering

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CHE 552 Process Dynamics and Control 2

Analog computation, time domain analysis, control of complex chemical systems. Prerequisite: Ch.E. 51 3 lectures, one term.

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CHE 554 Chemical Engineering Analysis

Application of advanced mathmetical techniques to the analysis of chemical engineering processes. Prerequisite: Permission of instructor. 3 lectures, one term.

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CHE 590 Introduction to Biochemical Engineering

Aspects of the biological sciences, primarily microbiology and biochemistry, of interest to the biological process industries (fermentation and food products) and to environmental pollution (air and water). Classification and growth characteristics of micro-organisms. Physico-chemical properties of biological compounds. Metabolism and biochemical kinetics. 3 hours lectures and laboratory, one term.

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CHE 591 Fermentation Processes

Methods of solving engineering problems imposed by both physical and biological factors in the food and fermentation technologies: the unifying principles of the processing operations involved in the production of antibiotics, yeasts, enzymes, beverage alcohol and other microbial products, and in biological waste treatment. Prerequisite: Ch. E. 590 (or permission of instructor) 3 hours lectures and laboratory, one term.

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CHE 592 Processing of Biological Materials

Methods of solving engineering problems imposed by both physical and biological factors in the food and fermentation technologies: a fundamental approach to formulation, preservation, and quality control procedures (mixing, extrusion, emulsification, heating, drying, irradiation, refrigeration, etc.). Prerequisite: Ch. E. 590 (or permission of instructor) 3 hours lectures, one term.

Graduate Course Descriptions

The Department of Chemical Engineering offers courses of study leading to the degree of Master of Applied Science (M. A. Sc.) and Doctor of Philosophy (Ph. D.). The Master of Applied Science programme may be followed in either one of two directions: a course-work (“professional-development”) option, which requires course work and an engineering design or analysis report; and a research option, which requires less course work and a research thesis. The first of these is intended to give a fuller understanding of fundamentals and greater mastery of the application of these principles to the solution of complex realistic problems. The second option offers training in fundamentals and in research methods, and is excellent preparation for those whose primary interest is a career in research. In addition to general and specialized graduate courses for research students, the Department offers a number of courses each year designed to be particularly suitable for the professional option in the M. A. Sc. programme. Graduate course requirements are measured in “units”. A course lasting one semester may be considered to be one unit. Normally, fame sinitsn mae saemantan Awn AAwni ane ld 2 ON Peed Lea EP ee at

The Master’s Degree Programme

The Ph.D. Programme

Research Activities

1 Biochemical Engineering

Chemical Kinetics and Catalysis

3 Process Control and Dynamics

4 Transport Phenomena

Department of Chemical Engineering 199

to carry fewer units.

In addition to the regular schedule, either option in the M. A. Sc. programme may be carried out on a co-operative basis. The professional option is particularly designed to meet the needs of a co-operative programme.

The professional option requires a total of eight units of course work in addition to the submission of an acceptable engineering report. Normally, at least five units of work will be chosen from courses offered by the Chemical Engineering Department. Other courses may be chosen from outside Departments or from other Chemical Engineering courses. The Engineering report will have a nominal value of one to two units, and represents evidence that the student is capable of obtaining and presenting a satisfactory solution to an original engineering problem of some complexity. The research option requires a total of four units of course work at the graduate level, in addition to the submission of a thesis reporting the results of original research. The courses to be taken will be selected in consultation with the student’s research advisor. However, it is expected that every student in the research option will take at least two courses offered by the Chemical Engineering Department.

The Ph.D. degree is awarded primarily for the successful completion of original research of high calibre. The general requirements are described in the section dealing with Graduate Studies and particular requirements are available from the Department of Chemical Engineering on request. The courses to be taken by a student in the Ph.D. programme will be determined by his Advisory Committe, and will normally consist of about four to eight units of work, in addition to the research thesis.

A student in the Ph.D. programme is not accepted as a candidate for the Ph.D. degree by this Department until he has presented and successfully defended to his Committe a proposal for research.

Graduate research may be pursued in a number of major areas of investigation which are listed below. In addition to work in these fields, a wide variety of research is carried out in less intensively developed areas.

Major areas of research are.

Heat transfer, mass transfer, and fluid flow in biological processes of industrial interest: chemical engineering design of fermentation, food processing and waste treatment facilities.

Investigation of reaction rates in inorganic and organic systems. Selectivity studies in catalysis, homogeneous catalysis, heat and mass transfer in heterogeneous systems; chemical reaction engineering.

Simulation, process control theory, applications of theory to actual chemical systems, computer control, process analysis and dynamics, operations research, optimal design, control of chemical plants.

Heat and mass transfer in gas-solid, gas-liquid, liquid-liquid, and other multiphase systems. Concurrent flow transport processes, boundary layer theory, turbulence at mobile interfaces, frequency response methods, diffusion studies, etc.

5 Polymer Science

6 Extractive Metallurgy

Details of Graduate Courses

Department of Chemical Engineering

Diffusion through modified membranes, radiation graft polymerization, emulsion polymerization, stress relationship in elastomers, physical properties of polymers, kinetics and thermodynamics of polymerization reactions, etc.

Pyrometallurgical, hydrometallurgical and electrometallurgical processes are studied in detail with emphasis being given to such subjects as solvent extraction, ion exchange, leaching, inorganic chemistry, theoretical high temperature metallurgy.

All courses are of one term duration and except for those listed under “Special Topics” are normally given every year.

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CHE 600 Theory and Application of Transport Phenomena

Derivation of general transport equations for mass, heat and momentum. Application and simplication of general equation to analysis of simple transfer operations. Volume and time averaging of the general equations for applications to transport processes and turbulent flow systems. Deductive analysis of the general equations and boundary layer theory. 3 lectures, one term.

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CHE 602 Behaviour and Properties of Particulate Material

Size analysis and description of particle. Behaviour and consequences of solid/solid and solid/fluid interactions, especially in dense systems. 3 lectures, one term.

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CHE 624 Liquid-fluid Transfer Processes

An advanced survey of gas-liquid heat and mass transfer operations in flowing systems. Special emphasis will be placed on one or more of the following topics: transfer mechanisms at fluid-liquid interfaces, drop and bubble phenomena, cascade theory of separation processes, transfer processes in two-phase tube flow, packed column behaviour, mass and heat transfer during mixing, boiling and condensation phenomena. 3 lectures, one term.

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CHE 134 Statistical Theory of Matter

Introduction to statistical methods, statistical description of systems of particles, statistical thermodynamics, techniques and results of statistical mechanics with applications, kinetic theory of transport, irreversible processes. 3 lectures, one term.

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CHE 535 Selected Applications of the Statistical Theory of Matter

Elementary kinetic theory of transport processes, systems of interacting particles, transport theory using the relaxation time approximation, near exact formulation of transport theory, irreversible processes and fluctuations. 3 lectures, one term.

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CHE 640 Chemical Reactor Analysis

Effects of mixing on chemical reactor performance, analysis of homogeneous and heterogeneous reactor stability and control, polymerization reactor analysis, optimal control of some chemical reactors. 3 lectures, one term.

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CHE 642 Chemical Thermodynamics and Kineticsfen n._mae

Review of laws of thermodynamics, Gibbs equation, thermochemistry, chemical reaction equilibrium kinetics of homogeneous and heterogeneous systems, techniques for kinetic parameter determination. 3 lectures, one term.

Department of Chemical Engineering

systems, reaction systems, and other chemical engineering processes. Topics cover the theory and applications of calculus of variations, linear and nonlinear programming, search techniques, dynamic programming, geometric programming, and maximum principle. 3 lectures, one term.

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CHE 672 Advanced Mathematics in Chemical Engineering

Review of fundamental concepts and methods of mathematical analysis with applications in Chemical Engineering. Topics will be selected from Advanced Calculus, Vector Analysis, Tensor Analysis, Matrix Algebra and Calculus, Ordinary and Partial Differential Equations and Integral Equations, with particular reference to the unifying concepts of functional analysis in Hilbert spaces. Prerequisite: Permission of Instructor. 3 lectures, one term.

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CHE 673 Advanced Mathematics in Engineering Research 80 Principles of Polymer Science

An extension of the techniques of Ch.E. 672, including Banach spaces, to problems in process analysis and control theory. Prerequisite: Ch.E. 672. 3 lectures, one term.

Introduction to the physical chemistry of high polymers, principles of polymer synthesis, mechanisms and kinetics of polymerization reactions, copolymerization theory, polymerization in homogeneous and heterogeneous systems, chemical reactions of polymers. Theory and experimental methods for the molecular characterization of polymers. 3 lectures, one term.

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CHE 681 Polymer Synthesis and Characterization

The synthesis of polymers of theoretical and industrial importance by ionic, free radical and condensation methods. Commercial and laboratory synthesis of monomers. Copolymerization. Crosslinking reactions. Polymerization kinetics and mechanisms. Stereoregulation of polymer structure. Correlation of polymer tacticity, branching and molecular weight distribution with the polymerization mechanism. Recent methods of polymer characterization. Prerequisite: ChE. 680. 3 lectures, one term.

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CHE 683 Physical Properties of Polymers

Molecular and morphological structure of high polymers, molecular interpretation of mechanical properties of solid polymers, phenomenological viscoelasticity, confirmation of polymeric chains. Transition phenomena, thermodynamics of polymers and kinetic theory of rubber elasticity. Rheology of polymer melts. Prerequisite: Ch.E. 680. 3 lectures, one term.

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CHE 684 Advanced Polymer Science

Selected advanced topics in the thermodynamics of polymer solutions, kinetics of polymerization, kinetics and thermodynamics of crystallization and melting, polymer degradation, transport phenomena in polymers. Prerequisite: Ch.E. 680. 3 lectures, one term.

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CHE 686 Topics in Hydrometallurgy

General discussion of hydrometallurgical systems; ionic processes in aqueous solutions, thermodynamics and kinetics of leaching, precipitation and reduction processes; design problems encountered in hydrometallurgical operations.

Department of Chemical Engineering

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CHE 687 Topics in Theoretical High Temperature Metallurgy

A number of topics of importance in high-temperature metal extraction will be discussed. Among these will be defects and transport properties in solids, mechanisms of oxide reduction and metal oxidation, trends in thermodynamic properties of compounds, and aspects of the physical

* chemistry of melts and slags.

‘8 Topics in Inorganic Chemistry

3 lectures, one term.

Selected topics of current interest in inorganic research and in application of inorganic chemistry and hydrometallurgy. 3 lectures, one term.

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CHE 589 Topics in Solvent Extraction and Ion Exchange

A discussion on the extraction and separation of metals by ion exchange and solvent extraction. This course will emphasize the main physico-chemical principles governing these processes. Selected industrial ion exchange and solvent extraction processes will be discussed to illustrate the application of basic principles in process design. 3 lectures, one term.

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CHE 690 Principles of Biochemical Engineering

Aspects of mass-transfer, heat-transfer and fluid flow (including rheology) related to the design of biological process equipment (food and fermentation products; waste treatment). Fermentations. Sterilization techniques. Extraction and separation methods. 3 lectures, one term.

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CHE 691 Advances in Biochemical Engineering Special Topics

Design and control of continuous-flow processes for biological systems. Insolubilized enzymes. Exploration of new methods of producing materials for food and medicinal purposes and of treating effluents. Prerequisite: Permission of instructor. 3 lectures, one term.

(Given only when justified by demand)

Group A - (Topics in Transport Phenomena)

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CHE 705 Particle-Fluid Dynamics

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CHE 707 Non-Newtonian Flow and Heat Transfer

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CHE 715 716, TA. 728

Selected Topics in Heat Transfer Heat Transfer in Two Phase System Use of Travelling Waves and Pulses to Measure Physica! Quantities Gas-Liquid Mass Transfer Processes

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CHE 749 Flow Through Porous Media

Group B - (Topics in Thermodynamics and Reaction Kinetics)

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CHE 735 Surface Chemistry

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CHE 741 Advanced Reactor Analysis

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CHE 744 Advanced Chemical Kinetics

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CHE 745 Physical Processes in Heterogeneous Catalysis

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CHE 746 Kinetics of Consecutive and Chain Reactions

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CHE 747 748

Kinetics of Biological Systems Reactor Flow Models and Reactor Stability

Group C - (Topics in Control Theory and Applied Mathematics)

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CHE 754 Mathematical Modelling of Chemical Processes

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CHE 756 Control of Complex Processes

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CHE 757 Optimization Problems in Chemical Processes

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CHE 765 Basic Statistics in Engineering

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CHE 766 Topics in Advanced Process Control

807.

808. 809.

Department of Chemical Engineering 203

Advanced Statistics in Engineering

Oral Examination for the Ph.D. Degree

Research Proposal for the Ph.D. programme

Comprehensive Examination

Graduate Research Seminar. (To be presented before submission of a thesis.)

Engineering Report. (For students in the course-work option. Topic suggested by student or faculty.)

Research Thesis for the M.A.Sc. Degree

Research Thesis for the Ph.D. Degree

{rts Quadrangle — Modern Languages Building

4 Department of Chemistry

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