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Chemistry (CHEM)

76 courses in the 1967–68 Undergraduate Calendar, read from the scanned original. The text comes from OCR, so check the scanned page before relying on a detail.

Notes

Faculty listed in 1967–68

H. G. McLeod, M.A., Ph.D. (Toronto) Professor and Chairman of Department W. F. Forbes, D.I.C., Ph.D., D.Sc. (London) - Professor Ww. A. E. McBryde, M.A. (Toronto), Ph.D. (Virginia) Professor and Dean of the Faculty of Science

T. Viswanatha, M.Sc., Ph.D. (Mysore) - Professor R. H. F. Manske, B.Sc., M.Sc. (Queen’s), Ph. D. (Manchester).

D.Sc. (Manchester), D.Sc. (McMaster), F.R.S.C. - Senior Lecturer G. F. Atkinson, M.A., Ph.D. (Toronto) - - Associate Professor D. A. Brisbin (Mrs.), ’B. Sc. (Alberta), Ph.D. (Toronto) - Associate Professor J. B. Capindale, M.A., D.Phil. (Oxford) - - Associate Professor W. L. Elsdon, M.Sc. (Western), Ph.D. (McGill) - Associate Professor R. M. Guest, M.A. (Western), Ph.D. (McGill) - Associate Professor D. E. Irish, B.Sc. (Western), M.Sc. (McMaster), Ph.D.

(Chicago) - - - Associate Professor D. Mackay, B.Sc., Ph.D. ( Aberdeen) - - Associate Professor A. D. Maynes, M.Sc., Ph.D. (Toronto) - - Associate Professor J. R. Mills, M.A. (Toronto), Ph.D. (Illinois) - Associate Professor J. B. Moffat, B.A., Ph.D. (Toronto) - - Associate Professor G. J. Palenik, B.Sc. (Illinois), Ph.D. (Southern California) Associate Professor A. Rudin, B.Sc. (Alberta), Ph.D. (Northwestern Associate Professor H. D. Sharma, M.Sc. (Delhi), Ph.D. (California) - Associate Professor G. E. Toogood, B.Sc., Ph.D. (Nottingham) - Associate Professor R. G. Woolford, M.Sc. (Western), Ph.D. (Illinois) — - Assistant Professor B. O. Fraser-Reid, M.Sc. (Queen’s), Ph.D. (Alberta) - Assistant Professor R. J. Friesen, M.Sc. (Manitoba - - - Assistant Professor T. E. Gough, B.Ss., Ph.D. (Leicester) - Assistant Professor V. A. Snieckus, B.Sc. (Alberta), M.S. (California.

Ph.D. (Oregon) - - Assistant Professor A. Balasubramanian, M.Sc. (Madras), Ph.D. (Indian Institute of

Science - I. I. Sc.) - - - - - Lecturer D. R. Raj (Mrs.), B.S. (Rochester), Ph.D. (Oregon) - - Lecturer W. J. Byars, H.N.C. (Dundee Technical College) Senior Demonstrator W. A. Cameron, H.N.C. (Hendon Technical College) Senior Demonstrator M. C. Michael (Miss) B.Sc. (Waterloo) - Senior Demonstrator G. Tomlinson, H.N.C. (North Staffordshire Technical

College) - - - - - Senior Demonstrator R. W. A. Oliver, B.Sc., M.Sc. (Bristol) - Visiting Adjunct Professor

Undergraduate Course Descriptions

Details of the undergraduate programmes offered by the Faculty of Science are to be found on page 99.

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CHEM 11 General Chemistry

An elementary study of the states of matter, changes of state, solution laws. Atomic structure and chemical bonding. Stoichiometry

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of equations. Oxidation-reduction. Chemical equilibria. Descriptive inorganic chemistry. 3 lectures, two terms. Laboratory: A term 3 hours alternate weeks.

B term 3 hours alternate weeks.

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CHEM 16 Introduction to General Chemistry

Introductory chemistry for Physical Education majors.

A concise introduction to the states of matter, atomic structure and bonding, oxidation/reduction, chemical equilibria and solution laws, organic chemistry. 3 hours lectures, one term.

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CHEM 22 Analytical Chemistry

Principles of quantitative analysis; precipitation, titration, separation, complex formation. Experiments in classical and modern methods of analysis, and problems on the necessary calculations.

1 lecture, 3 hours laboratory, one term.

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CHEM 25 Polymer Chemistry and Physics

The organic and physical chemistry of elementary polymerization reactions. A study of the physcial properties of polymeric materials as related to molecular structure. An introduction to polymer technology.

Prerequisite: Chem. 11 and Phys. 15.

3 lectures, one term.

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CHEM 26 Organic Chemistry I

The basic chemistry of the important classes of aliphatic and aromatic compounds.

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CHEM 31 Atomic and Molecular Structure

Introduction to the quantum-mechanical theory of chemical bonding. Atomic and molecular orbitals. The spatial arrangements of atoms and molecules. Methods of structure determination. Covalent bond lengths and angles. Crystal chemistry of ionic substances. The stereochemistry of various elements and their compounds.

3 lectures, one term.

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CHEM 35 Electrochemistry

Electrolytic conductance and transport. Thermodynamics of electrolytic solutions. Electrode potentials. The measurement of pH, Metallic corrosion.

Prerequisite: ChE 32. Chemistry 22.

3 lectures, 3 hours laboratory alternate weeks, one term.

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CHEM 36 Organic Chemistry II

An introduction to the important classes of heterocyclic compounds and natural products. A laboratory course on preparative organic chemistry and organic techniques accompanies the lectures. Prerequisite: Chemistry 26.

3 lectures, 3 hours laboratory, one term.

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CHEM 37 Biochemistry

Carbohydrates. lipids, proteins, hormones, nucleic acids, and vitamins. Metabolism of these groups of compounds. Physico-chemical aspects of biochemistry.

Prerequisite: Chemistry 36.

3 lectures, one term.

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CHEM 41 Nuclear and Radiochemistry

Structure, properties and reactions of nuclei. Quantitative treatment of radioactive processes. Radiation detection and measurement. Chemical applications.

3 lectures, one term.

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CHEM 45 Surface Phenomena

A study of absorption, wetting, foams, electrical surface phenomena, and principles of heterogeneous catalysis. 3 lectures, one term.

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CHEM 46 Organic Chemistry III

Selected topics in organic chemistry of interest and importance to Chemical Engineering students. 3 lectures, one term.

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CHEM 55 Polymer Physics and Chemistry

The Chemistry and physics of natural and synthetic polymers, covering the following topics: condensation and addition polymers and their reaction kinetics: properties of polymers, their measurement and relation to structure: isotactic polymers. copolymers, and polymer reactions.

3 lectures, one term.

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CHEM 101 General Chemistry

An elementary study of the states of matter, changes of state and the solution laws: stoichiometry; oxidation-reduction, chemical equilibria; descriptive chemistry of the common elements.

3 hours lectures, 3 hours laboratory for two terms.

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CHEM 131 General Chemistry

Elementary study of the states of matter, changes of state, solution laws; atomic structure and bonding; stoichiometry of equations, oxidation-reduction, chemical equilibria; descriptive chemistry of the commoner elements in terms of the periodic table.

3 lectures, 3 hours laboratory.

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CHEM 200 Radiochemistry

Stability rules for atomic nuclei; modes of decay of radioisotopes; radiations and their detection methods; nuclear reactions applied to activation analysis; radiation induced chemical reactions; use of radioisotopes in science and industry as tracers and radiation sources.

2 hours lectures, 3 hours laboratory, one term.

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CHEM 201 Introductory Inorganic Chemistry

Descriptive chemistry of the elements and their compounds based on the periodic table with special reference to metallurgical and other industrial processes. The laboratory will illustrate various methods of preparation of metals, non-metals and their compounds.

3 hours lectures, 3 hours laboratory, one term.

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CHEM 202 Analytical Chemistry

Theory and practice of analytical chemistry stressing wet methods in common use today. Treatment of analytical data to obtain meaningful information.

3 hours lectures, 9 hours laboratory, one term.

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CHEM 205 Introductory Physical Chemistry

Introduction to transport processes and reversible thermodynamics; reaction kinetics and phase equilibria. Thermo-

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dynamics of ideal gases. Diffusion, thermal conductivity and viscosity. Rates of simple reactions. Liquid-vapour equilibria. 3 hours lectures, 3 hours laboratory, one term.

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CHEM 206 Introductory Organic Chemistry

Basic Chemistry and structure of the important classes of aliphatic and aromatic compounds. 3 hours lectures, 3 hours laboratory, one term.

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CHEM 209 Technical Literature

Use of library; instruction and practice in searching technical literature; preparation of literature reviews, special topic assignments.

2 hours laboratory, one term.

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CHEM 231 Chemical Bonding and Structure: Classical and wave theories of the electronic structure of atoms developed and applied to the rationalisation of the periodic table and the problems of chemical bonding. The formation and properties of the covalent bond; bonding in ionic and metallic solids; methods for the establishment of the shapes of molecules

2 hours lectures, 3 hours laboratory. (Laboratories to be taken only by Honours Chemistry students).

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CHEM 232 Analytical Chemistry

Theory and practice of quantitive inorganic analysis. Representative classical and instrumental techniques will be carried out and studied with relation to the chemical phenomena which make them possible and to the general principles which they exemplify. A knowledge of ionic equilibria will be assumed and extended.

2 lectures, 6 hours laboratory.

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CHEM 235 Physical Chemistry I

A study of the thermodynamcis of ideal systems, the chemical kinetics of simple systems, and a short introduction to the phase rule.

2 lectures, 1 hour problems.

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CHEM 236 Organic Chemistry I

The properties, preparations, reactions, and basic structural theory of the common classes af aliphatic and aromatic compounds. A laboratory course on preparative organic chemistry accompanies the lectures. 2 lectures, 3 hours laboratory.

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CHEM 241 Principles and Application of Chemical Bonding: Classical and wave theories of the electronic structure of atoms developed and applied to the rationalisation of the periodic table and the problems of chemical bonding. Application to the systematic chemistry of the non-transition elements

2 hours lectures. 1 hour problems.

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CHEM 242 Chemical Analysis

The determination of inorganic chemical species by volumetric, gravimetric and selected instrumental procedures. The role of analysis as a service function will be stressed.

2 lectures, 6 hours laboratory.

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CHEM 301 Applied Inorganic Chemistry

The physical principles of bonding and structure developed and applied to such industrial processes and materials as extractive metallurgy, synthesis of industrial chemicals; ceramics and alloys. 3 hours lectures, 3 hours laboratory, one term.

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CHEM 303 Introductory Polymer Chemistry

The chemistry of natural and synthetic polymers, covering condensation and addition polymers, and their elementary reaction kinetics; properties of polymers, their measurement and relation to structure; isotactic polymers, copolymers and polymer reactions.

3 hours lectures, 3 hours laboratory, one term.

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CHEM 305 Applied Physical Chemistry

The application of reversible thermodynamics to chemical reactions. Kinetics of complex homogeneous and heterogeneous reactions. Chemical reactors. Phase equilibria applied to distillation and crystallization.

3 hours lectures, 3 hours laboratory, one term.

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CHEM 306 Applied Organic Chemistry

Petroleum chemistry; the production of important industrial chemicals; synthesis of dyestuffs pharmaceuticals, pesticides and surfactants.

3 hours lectures, 3 hours laboratory, one term.

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CHEM 307 Introductory Biochemistry

Carbohydrates; proteins; nucleic acids; lipids; metabolism of these compounds. 3 hours lectures, 3 hours laboratory, one term.

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CHEM 308 Instrumental ,Measurements I

Introduction to the use of instruments to obtain accurate measurements of physical and chemical properties of materials. 1 hour lecture, 3 hours laboratory, one term.

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CHEM 318 Instrumental Measurements II

Extension of Chemistry 308 to dynamic measurements following the course of a chemical reaction or monitoring a continuous process.

1 hour lecture, 3 hours laboratory, one term.

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CHEM 325 Physical Chemistry

An introduction to the study of matter from the macroscopic and molecular point of view. Classical kinetic theory of gases, thermodynamics, electrochemistry, kinetics, molecular structure, surface phenomena, phase equilibria and macromolecules. A knowledge of calculus is assumed.

2 lectures, 3 hours laboratory.

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CHEM 331 Inorganic Chemistry I: Systematic inorganic chemistry of the nontransition elements based on the principles established in Chemistry 231

introduction to nuclear-and radio-chemistry. The laboratory illustrates methods.

of synthesis and characterization of typical inorganic compounds. 2 hours lectures, 3 hours laboratory (except for Honours Chemistry and Physics students).

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CHEM 335 Physical Chemistry II

The thermodynamics of systems of variable composition including real gases and binary solutions of non-electrolytes. Electrochemistry and the thermodynamics of electrolytic solutions.

2 lectures, 6 hours laboratory.

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CHEM 336 Organic Chemistry II: Correlation between electronic structure and chemical properties and reactivity; stereochemistry; synthetic methods, especially enolate and related condensations, and cyclo-addition reactions; carbohydrate and peptide chemistry. 2 hours lectures, 3 hours laboratory

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CHEM 337 Biochemistry I

Carbohydrates, lipids, proteins, hormones, nucleic acids, and vitamins. Metabolism of these groups of compounds. Physico-chemical aspects of biochemistry.

Prerequisite: Chem. 236 or equivalent.

2 lectures. (For General students and Honours Biology. 3 hours laboratory).

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CHEM 341 Inorganic and Nuclear Chemistry

The chemistry of the transition elements. Introduction to nuclear and radiochemistry. 2 lectures, 3 hours laboratory.

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CHEM 400 Electrochemistry and Corrosion

Electrolytic conductance and transport; thermodynamics of electrolytic solutions; electrode potentials; the measurement of pH; metallic corrosion.

3 hours lectures, 3 hours laboratory alternate weeks, one term.

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CHEM 402 Modern Organic Analysis

Application of wet chemical and instrumental methods in current use to the identification, determination and characterization of organic materials.

2 hours lectures, 3 hours laboratory, one term.

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CHEM 403 Physical Chemistry of Polymers

Polymerization kinetics including condensation polymers, free radical, ionic and stereoregular addition polymers, and copolymers; structure of polymers molecules; degradation; solution properties of crystalline and amorphous polymers; molecular weight. distributions.

3 hours lectures, 3 hours laboratory, one term.

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CHEM 405 Surface Chemistry

An introduction to the physical chemistry of surfaces. Properties of surfaces; quantitative description of a surface; interaction between phases at a surface. Thermodynamic treatment of surfaces; physical adsorption; chemisorption. Practical applications of surface chemistry in chemical industry.

3 lectures, one term.

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CHEM 407 Applied Biochemistry

Vitamins and hormones; chemistry, production, and mechanism of action of drugs; industrial applications of enzymes and other biological materials.

3 lecture hours, 3 hours laboratory, one term.

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CHEM 408 Instrumentation I

Introductory systems approach to chemical instruments. Input transducers, electronic and electromechanical modules, readout devices. Optimum operation of instruments. Control systems.

1 hour lecture, 3 hours laboratory, one term.

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CHEM 412 Analysis of Materials

Techniques of separation determination and characterization of complex materials including ores, resistant alloys, ceramics, synthetic polymers, food and drug products and pesticides.

2 hours lectures, 3 hours laboratory, one term.

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CHEM 413 Properties of Polymers

Behaviour of polymers: types of mechanic behaviour, flow and relaxation mechanism, birefringence, orientation and recovery; glass transitions; crystallisation and properties of crystalline polymers; introduction to theory of high elasticity.

3 hours lectures, 3 hours laboratory, one term.

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CHEM 415 Catalysis

An introduction to homogeneous and heterogeneous catalysis; chemisorption and its relation to catalysis; geometrical and electronic factors. Industrial applications of catalysis. Problems in selection of catalysts.

3 lectures, one term.

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CHEM 418 Instrumentation II

The laboratory time will be divided between analytical study of instrument modules, and synthesis of an instrument system to meet a typical industrial need.

1 hour lecture, 3 hours laboratory, one term.

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CHEM 431 Inorganic Chemistry II: Systematic inorganic chemistry of the transition elements; introduction to selected topics including ligand field theory; magnetochemistry; interpretation of electronic spectra

2 hours lectures.

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CHEM 435 Physical Chemistry III

Introduction to quantum chemistry and statistical thermodynamics. Applications to kinetics. surface chemistry, and spectroscopy. 2 lectures, 1 hour problems.

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CHEM 436 Organic Chemistry III

The use of spectroscopic techniques in organic chemistry; analysis of reaction mechanisms; free radical chemistry; a brief introduction to natural product chemistry.

2 hours lectures.

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CHEM 437 Biochemistry II

Selected topics and techniques in modern biochemistry; energy transfer, transport across membranes, comparative aspects of metabolism, mechanism and kinetics of enzyme activity, structural macromolecules, 2 lectures, 3 hours laboratory.

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CHEM 439 Advanced Laboratory

An introduction to research methods and techniques. The student will elect to concentrate this study in one of the following fields of chemistry, viz. analytical, inorganic, organic, physical or biochemistry. Honours Chemistry Students, 6 hours laboratory.

Honours Chemistry and Physics Students, 3 hours laboratory.

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and their reaction kinetics; properties of polymers, their measurements and relation to structure; isotactic polymers, copolymers, and polymer reactions. 2 lectures.

Graduate Programme in Chemistry

For both the M.Sc. and Ph.D. programmes, a student is expected to combine a thesis embodying the results of some original research with course work. A major field of study should be chosen from the following areas: analytical, inorganic, organic (including biochemistry) and physical chemistry. Course work will be appropriate to the area selected and a research director should

be chosen from members of the department who are presently engaged in various fields of endeavour as listed.

Major Areas of Research

Analytical Chemistry - chemical instrumentation based on analog modules; continuous analysis by spectrophotometric or electroanalytical techniques; complex ion systems useful in analysis; application of physical methods e.g., ion exchange, solvent extraction, to separation of metallic constituents in aqueous solutions; analysis of rocks, minerals and meteorites.

Inorganic Chemistry - studies on inorganic complexes in solution, magnetic ity measurements of metallic complexes; structure determination by

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(using infrared, ultraviolet and electron spin resonance techniques) cular conformation and hydrogen bonding.

Biochemistry - effects of irradiation on proteins and aminoacids as studied by electron spin resonance and other techniques; the aging process; synthetic and degradative studies on enzymes, peptides and proteins; nature of materials

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Physical Chemisiry - studies in moiten salt chemistry, especially mass transport phenomena; kinetics of polymer reactions; experimentai and theoretical studies of surfaces, surface reactions and catalysis; quantum chemical calculations on organic molecules; electrochemistry and especially electroplating mechanisms and corrosion studies; spectroscopic studies of species in solution to determine their identity and contribution to the properties of the system.

Details regarding these programmes and the faculty members engaged in them are to be found in a booklet prepared by the Chemistry Department. The booklet also discusses admission procedures, programs of study, teaching and research facilities and equipment and is sent to every potential graduate student who applies for admission. New areas of research are usually added each year.

Graduate Course Descriptions

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CHEM 610 Advanced Nuclear and Radiochemistry

Systematics of atomic nuclei; nuclear models; radioactive decay processes; nuclear reactions; interaction of - radiation with matter; radiation detection methods and radiochemical assay; tracers in chemical applications; radiochemical techniques and _ radiation chemistry.

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CHEM 615 Physical Chemistry of High Polymers

Selected topics in the field.

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CHEM 620 Resonance Spectroscopy

Nuclear and electron magnetic resonance spectroscopy; basic principles, derivation and solution of the Bloch Equations, first and second-order interpretation of nuclear magnetic resonance spectra. The application of these techniques and of double irradiation experiments to selected chemical problems.

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CHEM 621 Physical Methods of Inorganic Chemistry

The application of various spectroscopic techniques to problems in Inorganic Chemistry; advanced ligand field theory.

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CHEM 630 X-ray Crystallography

Principles and practice of X-ray, neutron and electron diffraction. Interpretation of diffraction data for structure determinations of inorganic and organic compounds.

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CHEM 631 Coordination Chemistry

Equilibrium and kinetic aspects of complex species; experimental and calculative techniques for the determination of stability constants; inorganic reaction mechanisms; non-aqueous solvents.

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CHEM 632 Chemical Analysis

An advanced treatment of classical analysis. The application of equilibria and kinetic considerations to the study of deviations from stoichiometric behaviour. The formation and nature of precipitates, nonaqueous solvent methods. analytical separations.

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CHEM 635 Thermodynamics

A rigorous treatment of chemical thermodynamics with emphasis on the complete thermodynamic description of a system.

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CHEM 636 Natural Products

Selected topics in the field of natural products; heterocyclic and alkaloid chemistry; steroids and terpenes, with emphasis on structural determination and biogenesis.

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CHEM 637 Advanced Biochemistry

Selectéd topics in the field.

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CHEM 642 Chemical Instrumentation

Instrument components and optimum application; rudiments of design; electrical, spectral, migrational and other methods.

Department of Chemistry

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CHEM 645 Molecular Quantum Mechanics

A course on the quantum theoretical elucidation of chemical and physical properties of molecules. Quantum mechanical principles. Quantum mechanical techniques, perturbation and variation methods. Molecular orbital method. Nature of chemical binding.

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CHEM 646 Theoretical Organic Chemistry

The structure and reactivity of organic molecules emphasizing stereochemistry and reaction mechanisms.

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CHEM 647 Selected Topics in Physical Biochemistry

Discussion of several related fields covering the application of spectroscopic methods to biochemistry; ultracentrifugation; light scattering; and tracer chemistry.

‘655. Chemical Kinetics. Statistical methods applied to the kinetic molecular theory and to the treatment of interacting systems. The kinetics of homogenous reactions in gases with emphasis on unimolecular reactions, and of reactions in condensed phases.

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CHEM 656 Synthetic Methods of Organic Chemistry

A discussion of classical and newer concepts in the synthesis of organic compounds with emphasis placed on the fundamental behaviour patterns. An integration of experimental facts and modern theories is presented. —

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CHEM 662 Colloquia on Current Topics in Inorganic and Analytical Chemistry

Graduate students will each present for discussion short colloquia based on their reading of assigned topics. Participation in the discussions, as well as the actual presentation of papers, will be an integral part of the course. Admission to this course will be at the discretion of the Inorganic and Analytical faculty.

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CHEM 665 Molecular Spectroscopy

Rotational and vibrational spectra of diatomic and polyatomic molecules. Interpretation of infrared and Raman spectra. Group theory and molecular symmetry. Applications.

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CHEM 666 Organic Spectroscopy

Introduction to ultraviolet, infrared, and resonance spectroscopy, with emphasis on applications to studies of organic molecules.

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CHEM 675 Selected Topics in Physical Chemistry

Discussion of specialized topics in thermodynamics, electrochemistry, surface phenomena and quantum chemistry at an advanced level.

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CHEM 685 Physical Chemistry of Surfaces

Thermodynamics of the adsorbed phase. Heats of adsorption. Surface heterogenity. The adsorption isotherm. Statistical mechanics of adsorption. Chemisorption and catalysis. Kinetics of adsorption chemisorption. The nature of adsorptive forces. Quantum mechanics applied to surface phenomena.

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CHEM 699 Thesis

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