CHEM 21 Inorganic Chemistry
Systematic inorganic chemistry based on the periodic classification, with emphasis on the relationship between properties and structure.
3 lectures, one term.
44 courses in the 1965–66 Undergraduate Calendar, read from the scanned original. The text comes from OCR, so check the scanned page before relying on a detail.
3 lectures, two terms. Laboratory: A term 3 hours alternate weeks.
B term 3 hours.
Systematic inorganic chemistry based on the periodic classification, with emphasis on the relationship between properties and structure.
3 lectures, one term.
Principles of quantitative analysis; precipitation, titration, separation, complex formation. Experiments in classical and modern methods of analysis, and problems on the necessary calculations.
1 lecture, 3 hours laboratory, one term.
The organic and physical chemistry of elementary polymerization reactions. A study of the physical properties of
polymeric materials as related to molecular structure. An introduction to polymer technology.
Prerequisite: Chem. 11 and Phys. 15.
3 lectures, one term.
The basic chemistry of the important classes of aliphatic and aromatic compounds.
Introduction to the quantum-mechanical theory of chemical bonding. Atomic and molecular orbitals. The spatial arrangements of atoms and molecules. Methods of structure determination. Covalent bond lengths and angles. Crystal chemistry of ionic substances. The stereochemistry of various elements and their compounds.
3 lectures, one term.
Electrolytic conductance and transport. Thermodynamics of electrolytic solutions. Electrode potentials. The measurement of pH. Metallic corrosion.
Prerequisite: ChE 32, Chemistry 22.
3 lectures, 3 hours laboratory alternate weeks, one term.
An introduction to the important classes of heterocyclic compounds and natural products. A laboratory course on preparative organic chemistry and organic techniques accompanies the lectures. Prerequisite: Chemistry 26.
3 lectures, 3 hours laboratory, one term.
Carbohydrates, lipids, proteins, hormones, nucleic acids, and vitamins. Metabolism of these groups of compounds. Physico-chemical aspects of biochemistry.
Prerequisite: Chemistry 36.
3 lectures, one term.
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Department of Chemistry
Structure, properties and reactions of nuclei. Quantitative treatment of radioactive processes. Radiation detection and measurement. Chemical applications.
3 lectures, one term.
A study of absorption, wetting, foams, electrical surface phenomena, and principles of heterogeneous catalysis. 3 lectures, one term.
Selected topics in organic chemistry of interest and importance to Chemical Engineering students. 3 lectures, one term.
The Chemistry and physics of natural and synthetic polymers, covering the following topics: condensation and addition polymers and their reaction kinetics: properties of polymers, their measurement and relation to structure; isotactic polymers, copolymers, and polymer reactions.
3 lectures, one term.
Elementary study of the states of matter, changes of state, solution laws; atomic structure and bonding; stoichiometry of equations, oxidation-reduction, chemical equilibria; descriptive chemistry of the commoner elements in terms of the periodic table.
3 lectures, 3 hours laboratory.
Classical and wave theories of the electronic structure of atoms developed and applied to the rationalization of the periodic table and the problems of chemical bonding. The formation and properties of the covalent bond. Bonding in ionic and metallic solids. Methods for the establishment of the shape of molecules.
2 lectures (For General students, 1 hour problem.)
Theory and practice of quantitative inorganic analysis. Representative classical and instrumental techniques will be carried out and studied with relation to the chemical phenomena which make them possible and to the general principles which they exemplify. A knowledge of ionic equilibria will be assumed and extended.
2 lectures, 6 hours laboratory.
A study of the thermodynamics of ideal systems, the chemical kinetics of simple systems, and a short introduction to the phase rule.
2 lectures, 1 hour problems.
The properties, preparations, reactions, and basic structural theory of the common classes of aliphatic and aromatic compounds. A laboratory course on preparative organic chemistry accompanies the lectures. 2 lectures, 3 hours laboratory.
The determination of inorganic chemical species by volumetric, gravimetric and selected instrumental procedures. The role of
analysis as a service function will be stressed. 2 lectures, 6 hours laboratory.
An introduction to the study of matter from the macroscopic and molecular point of view. Classical kinetic theory of gases, thermodynames, electrochemistry, kinetics, molecular structure, surface phenomena, phase equilibria and macromolecules. A knowledge of Calculus is assumed.
2 lectures, 3 hours laboratory.
Systematic inorganic chemistry based on the electronic configuration of the elements and the periodic properties related thereto. Principles of bonding are reviewed and extended. An introduction to nuclear chemistry and coordination chemistry is included. The laboratory will illustrate methods of synthesis and characterization of typical inorganic compounds.
2 lectures; laboratory for General or Chemistry and Biology students 3 hours for Chemistry students see Chemistry 431; for Chemistry and Physics students see Chemistry 439.
The thermodynamics of systems of variable composition including real gases and binary solutions of non-electrolytes. Electrochemistry and the thermodynamics of electrolytic solutions.
2 lectures, 6 hours laboratory.
Chemistry 236 expanded to stress enolate condensations and alicyclic compounds, stereochemistry, and reaction mechanisms. The laboratory course includes further preparative work and qualitative organic analysis.
2 lectures, 3 hours laboratory.
Carbohydrates, lipids, proteins, hormones, nucleic acids, and vitamins. Metabolism of these groups of compounds. Physico-chemical aspects of biochemistry.
Prerequisite: Chem. 236 or equivalent.
2 lectures. (For General students, 3 hours jaboratory).
A more advanced discussion of recent developments in inorganic chemistry selected from such topics as the stabilities and reaction mechanisms of inorganic complexes, carbonyls and related compounds, iso- and heteropoly-acids, intermetallic compounds and alloys, nonstoichiometric compounds, recent chemistry of the lanthanides and actinides and other less familiar elements. The laboratory will stress the application of physical methods to the determination of the structure and properties of compounds of current interest.
2 lectures, 6 hours laboratory.
Introduction to quantum chemistry and statistical thermodynamics. Applications to kinetics, surface chemistry, and spectroscopy. 2 lectures, | hour problems.
Department of Chemistry
A selection of more advanced topics to include heterocyclic compounds, natural products, and theoretical aspects of organic chemistry. 2 lectures.
Selected topics and techniques in modern biochemistry; energy transfer, transport across membranes, comparative aspects of metabolism, mechanism and kinetics of enzyme activity, structural macromolecules. 2 lectures, 3 hours laboratory.
439, Advanced Laboratory. An introduction to research methods and techniques. The student will elect to concentrate this study in one of the following fields of chemistry, viz. analytical, inorganic, organic, physical or biochemistry. Honours Chemistry Students, 6 hours laboratory.
Honours Chemistry and Physics Students, 3 hours laboratory.
The chemistry and physics of natural and synthetic polymers, covering the following topics: condensation and addition polymers and their reaction kinetics; properties of polymers, their measurements and relation to structure; isotactic polymers, copolymers, and polymer reactions.
2 lectures.
Graduate Programme in Chemistry
For both the M.Sc. and Ph.D. programmes, a student is expected to combine a thesis embodying the results of some original research with course work. A major field of study should be chosen from the following areas: analytical, inorganic, organic (including biochemistry) and physical chemistry. Course work will be appropriate to the area selected and a research director should be chosen from members of the department who are presently engaged in various fields of endeavour as listed.
Major Areas of Research
Analytical Chemistry - chemical instrumentation based on analog modules; continuous analysis by spectrophotometric or electroanalytical techniques; complex ion systems useful in analysis; application of physical methods e.g., ion exchange, solvent extraction, to separation of metallic constituents in aqueous solutions.
Inorganic Chemistry - studies on inorganic complexes in solution, magnetic susceptibility measurements of metallic complexes; crystal structure of salt hydrates; solutions of metals in molten salts and other non-aqueous media; the chemistry of the lanthanides in non-aqueous solvents.
Organic Chemistry - synthesis of organic substances by electrochemical techniques; abnormal Kolbe reaction of halogenocarboxylic acids; free radical chemistry in general and especially the synthesis and decomposition of peroxyand azo-compounds; studies on heterocyclic compounds; spectroscopic studies (using infrared, ultraviolet and electron spin resonance techniques) of molecular conformation and hydrogen bonding.
Biochemistry - effects of irradiation on proteins and aminoacids as studied by electron spin resonance and other techniques; the aging process; synthetic and degradative studies on enzymes, peptides and proteins; nature of materials excreted by algae.
Physical Chemistry - studies in molten salt chemistry, especially mass transport phenomena; kinetics of polymer reactions; experimental and theoretical studies of surfaces, surface reactions and catalysis; quantum chemical calculations on organic molecules; electrochemistry and especially electroplating mechanisms and corrosion studies; spectroscropic studies of species in solution to determine their identity and contribution to the properties of the system.
Details regarding these programmes and the faculty members engaged in them are to be found in a booklet prepared by the Chemistry Department. The booklet also discusses admission procedures, programs of study, teaching and research facilities and equipment and is sent to every potential graduate student who applies for admission. New areas of research are usually added each year.
Graduate Course Descriptions
Equilibrium and kinetic aspects of complex species; experimental and calculative techniques; mechanism of reactions of co-ordination compounds.
An advanced treatment of classical analysis. The application of equilibria and kinetic considerations to the study of deviations from stoichiometric behaviour. The formation and nature of precipitates, nonaqueous solvent methods, analytical separations.
A rigorous treatment of chemical thermodynamics with emphasis on the complete thermodynamic description of a system.
Selected topics in the field of natural products stressing the use of spectral and other physico-chemical methods in the determination of structure.
Instrument components and optimum application; rudiments of design; electrical, spectral, migrational and other methods.
A course on the quantum theoretical elucidation of chemical and physical properties of molecules. Quantum mechanical principles. Quantum mechanical techniques, perturbation and variation methods. Molecular orbital method. Nature of chemical binding.
The structure and reactivity of organic molecules emphasizing stereochemistry and reaction mechanisms.
Statistical methods applied to the kinetic molecular theory and to the treatment of interacting systems. The kinetics of homogenous reactions in gases with emphasis on unimolecular reactions, and of reactions in condensed phases.
Department of Chemistry
A discussion of classical and newer concepts in the synthesis of organic compounds with emphasis placed on the fundamental behaviour patterns. An integration of experimental facts and modern theories is presented.
Graduate students will each present for discussion short colloquia based on their reading of assigned topics. Participation in the discussions, as well as the actual presentation of papers, will be an integral part of the course. Admission to this course will be at the discretion of the Inorganic and Analytical faculty.
The determination of the structure of polyatomic molecules from the study of infrared and Raman spectra. Applications in thermodynamics.
Introduction to ultraviolet, infrared, and resonance spectroscopy, with emphasis on applications to studies of organic molecules.
Selected topics of interest to biologists, biochemists and biophysicists will be presented at the advanced level with the aim of evaluating recent work and development in each area. Each will be developed from basic concepts and interrelationships emphasized. Topics will include: the structure of proteins and their properties in solution, transport through biological membranes, cell morphology and physiology, structure and function of selected organells, biosynthesis of macromolecules, and the chemistry of enzyme action. This graduate course is to be presented by members of the Biology, Chemistry and Physics departments and is intended to cover those areas common to these disciplines (identical to Biology 667 and Physics 667).
Discussion of specialized topics in thermodynamics, electrochemistry, surface phenomena and quantum chemistry at an advanced level.
Thermodynamics of the adsorbed phase. Heats of adsorption. Surface heterogenity. The adsorption isotherm. Statistical mechanics of adsorption. Chemisorption and catalysis. Kinetics of adsorption chemisorption. The nature of adsorptive forces. Quantum mechanics applied to surface phenomena.
Department of Civil Engineering
A. N. Sherbourne, B.Sc. (London), B.S., M.S. (Lehigh), M.A., Ph.D. (Cambridge) - Professor and Chairman of the Department S. T. Ariaratnam, B.S. (Ceylon), B.Sc. (Eng.) (Ceylon).
B.Sc., M.S. (London), Ph.D. (Cambridge) - - - Professor M. Z. Cohn, C.E., Candidate of Tech. Sc. (Bucharest) - Professor W. R. Drynan, B.A.Sc. (Toronto), M.S., Ph.D. (Texas) - Professor N. C. Lind, M.S. (Royal Technical University of Denmark).
Ph.D. (Illinois) - = ee ele Professor
D. T. Wright, B.A.Sc. (Toronto), M.S. (Illinois), Ph.D. (Cambridge) Professor and Dean of the Faculty of Engineering C. P. Fisher, B.A.Sc. (Toronto), Ph.D. (Texas) - Associate Professor W. A. McLaughlin, B.Eng. (Saskatchewan), M.S. (Purdue) Associate Professor H. B. Poorooshasb, B.Sc. (Manchester), Ph.D. (Cambridge) Associate Professor
J. D. Scott, B.Sc., (Queen’s), M.S., Ph.D. (Illinois), - Associate Professor R. Green, B.Sc. (Eng.) (London), M.Sc. (Queen' s), M.Sc.
(Waterloo) - - Assistant Professor V. K. Handa, B.Sc. (Calcutta), BSc. (Eng.) (London), M.Sc.
(Queen’s), M.Sc., Ph.D. (Waterloo) - - Assistant Professor H. M. Hill, B.Eng., M.S. (Saskatchewan) - - - Assistant Professor B. G. Hutchinson, B.E. (Sydney), M.Sc. (Queen’s) - Assistant Professor J. Shortreed, B.Eng.Sc. (Western), M.Sc. (Queen’s) - Assistant Professor T. H. Topper, B.A.Sc. (Toronto), Ph.D. (Cambridge) - Assistant Professor O. L. White, B.Sc. (Melbourne,) M.A.Sc. (Toronto) - Assistant Professor B. LeLievre, B.Eng. (West Australia), M.A.Sc. (Waterloo) - Lecturer P. H. Meincke, B.Sc. (Manitoba) - - - - Lecturer
Undergraduate Course Descriptions
CE 22. Mechanics of Deformable Solids II. A general treatment of the behaviour of structural components from the study of stress and strain in solids. Topics include Mohrs circle for stresses, strains and moments of inertia, superposition, theories of failure, elastic and inelastic analysis of unsymmetrical bending, shear centre, torsion of cellular members, columns and stability, virtual work, complementary energy, and an introduction to beams on elastic foundations.
CE 31. Theory of Structures. Analysis of simple determinate and indeterminate structures. Topics include static and moving loads on beams and trusses; influence lines; cables; deflections by virtual work, moment area and Williot Mohr; methods of superposition, slope deftection and moment distribution.
CE 32. Behaviour of Steel Structures. Plastic analysis and the behaviour of structural elements in steel. Topics include inelastic behaviour of steel members, basic theorems of plastic collapse, methods of plastic analysis, beams, tension and compression members, connections.
CE 33. Reinforced Concrete I. Pysico-mechanical properties of steel and concrete. Behaviour of reinforced concrete members. Ultimate strength analysis and design of members in pure or combined compression, tension and bending, shear and torsion. Elastic analysis and design. Cracking and deflections of R.C. members. Standard recommendations.
CE 34. Reinforced Concrete H. Structural considerations in concrete design. Safety, rigidity, stability. Design of redundant beams. Reinforced concrete